Advances in Physical Organic Chemistry

Advances in Physical Organic Chemistry

by John P. Richard
     
 

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ISBN-10: 0123860474

ISBN-13: 9780123860477

Pub. Date: 12/13/2011

Publisher: Elsevier Science

Advances in Physical Organic Chemistry provides the chemical community with authoritative and critical assessments of the many aspects of physical organic chemistry. The field is a fast developing one, with results and methodologies in applications from biology to solid state physics.

The previous volumes in this serial constitute a lasting record of

Overview

Advances in Physical Organic Chemistry provides the chemical community with authoritative and critical assessments of the many aspects of physical organic chemistry. The field is a fast developing one, with results and methodologies in applications from biology to solid state physics.

The previous volumes in this serial constitute a lasting record of this field and will continue to do so as they are widely used and cited. Readers will also benefit from the comprehensive subject and citation index.

Product Details

ISBN-13:
9780123860477
Publisher:
Elsevier Science
Publication date:
12/13/2011
Series:
Advances in Physical Organic Chemistry Series
Pages:
272
Product dimensions:
5.90(w) x 9.10(h) x 0.70(d)

Table of Contents


Editor's Preface     ix
Contributors to Volume 42     xi
Cycloaromatization reactions: the testing ground for theory and experiment   Igor Alabugin   Boris Breiner   Mariappan Manoharan     1
Introduction: bonds lost and bonds formed, or chemical bookkeeping     1
Cycloaromatization reactions: breaking [pi]-bonds and breaking the rules     2
The diversity of cycloaromatization reactions     3
The relative role of [sigma]- versus [pi]-effects at the early reaction stage     6
[sigma]-Effects on reactant stability     10
[pi]-Effects on reactant stability     22
Transition state effects: communication of orthogonal orbitals in the transition state of radical-anionic cyclizations     23
Effects on product stability     27
Conclusion     31
References     31
N-Acyloxy-N-alkoxyamides - structure, properties, reactivity and biological activity   Stephen A. Glover     35
Introduction     35
Synthesis     39
Structure     43
Chemical reactivity     59
Biological activity of N-acyloxy-N-alkoxyamides     97
Conclusions     115
Acknowledgements     116
References     117
The Interplay between experiment and theory: computational NMR spectroscopy of carbocations   Hans-Ullrich Siehl     125
Introduction     125
Alkyl and cycloalkylmethyl cations     126
Vinyl cations     133
Cycloalkyl cations     142
[mu]-Hydrido-bridged carbocations     144
Bicyclic and polycyclic carbocations     145
[pi]-Stabilized carbocations     150
Heteroatom stabilized carbocations     156
Final remarks     158
Conclusions     160
Acknowledgments     160
References     160
Dynamics of guest binding to supramolecular systems: techniques and selected examples   Tamara C.S. Pace   Cornelia Bohne     167
Introduction     167
Techniques     169
Examples of supramolecular dynamics studies     185
Conclusions     216
Acknowledgements     217
References     217
Mechanisms of oxygenations in zeolites   Edward L. Clennan     225
Introduction     225
Zeolites     226
Experimental considerations     230
Intrazeolite photooxygenations     232
Acknowledgement     261
References     262
Metal-catalyzed alcoholysis reactions of carboxylate and organophosphorus esters   R. Stan Brown   Alexei A. Neverov     271
Introduction     271
Background theory     274
Titrations in alcohol     276
Metal ion alcoholysis and titration in alcohol     278
Transition metal ion and Ln[superscript 3+] catalysts of transesterifications of neutral carboxylate and organophosphate esters     284
Transition metal ion and La[superscript 3+]-catalysis of the alcoholysis of phosphate diesters     308
Conclusions     324
Acknowledgements     325
References     325
Author Index     333
Cumulative Index of Authors     351
Cumulative Index of Titles     353
Subject Index     363

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