Spectrometric Identification of Organic Compounds / Edition 7

Spectrometric Identification of Organic Compounds / Edition 7

by Robert M. Silverstein, Francis X. Webster, David J. Kiemle
     
 

ISBN-10: 0471393622

ISBN-13: 9780471393627

Pub. Date: 01/28/2005

Publisher: Wiley

Originally published in 1962, this was the first book to explore teh identification of organic compounds using spectroscopy. It provides a thorough introduction to the three areas of spectrometry most widely used in spectrometric identification: mass spectrometry, infrared spectrometry, and nuclear magnetic resonance spectrometry. A how-to, hands-on teaching

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Overview

Originally published in 1962, this was the first book to explore teh identification of organic compounds using spectroscopy. It provides a thorough introduction to the three areas of spectrometry most widely used in spectrometric identification: mass spectrometry, infrared spectrometry, and nuclear magnetic resonance spectrometry. A how-to, hands-on teaching manual with considerably expanded NMR coverage—NMR spectra can now be intrepreted in exquisite detail. This book:

• Uses a problem-solving approach with extensive reference charts and tables.

• Offers an extensive set of real-data problems offers a challenge to the practicing chemist

Product Details

ISBN-13:
9780471393627
Publisher:
Wiley
Publication date:
01/28/2005
Edition description:
REV
Pages:
512
Product dimensions:
8.78(w) x 11.06(h) x 0.91(d)

Table of Contents

Chapter 1. Mass Spectrometry.

1.1 Introduction.

1.2 Instrumentation.

1.3 Ionization Methods.

1.4 Mass Analyzers.

1.5 Interpretation of El Mass Spectra.

1.6 Mass Spectra of Some Chemical Classes.

Chapter 2. Infrared Spectrometry.

2.1 Introduction.

2.2 Theory.

2.3 Instrumentation.

2.4 Sample Handling.

2.5 Interpretations of Spectra.

2.6 Characteristic Group Absorption of Organic Molecules.

Chapter 3. Proton Magnetic Resonance Spectrometry.

3.1 Introduction.

3.2 Theory.

3.3 Instrumentation and Sample Handling.

3.4 Chemical Shift.

3.5 Spin Coupling, Multiplets, Spin Systems.

3.6 Protons on Oxygen, Nitrogen, and Sulfur Atoms. Exchangeable Protons.

3.7 Coupling of Protons to Other Important Nuclei (19F, E, 31P, 29Si, and 13C.

3.8 Chemical Shift Equivalence.

3.9 Magnetic Equivalence (Spin-Coupling Equivalence).

3.10 AMX, ABX, and ABC Rigid Systems with Three Coupling Constants.

3.11 Confirmationally Mobile, Open-Chain Systems. Virtual Coupling.

3.12 Chirality.

3.13 Vicinal and Geminal Coupling.

3.14 Low-Range Coupling.

3.15 Selective Spin Decoupling. Double Resonance.

3.16 Nuclear Overhauser Effect, Difference Spectrometry, 1H 1H Proximity Through Space.

Chapter 4. Carbon-13 NMR Spectrometry.

4.1 Introduction.

4.2 Theory.

4.3 Interpretation of a Simple 13C Spectrum: Diethyl Phthalate.

4.4 Quantitative 13C Analysis.

4.5 Chemical Shift Equivalence.

4.6 DEPT.

4.7 Chemical Classes and Chemical Shifts.

Chapter 5. Correlation NMR Spectrometry; 2-D NMR.

5.1 Introduction.

5.2 Theory.

5.3 Correlation Spectrometry.

5.4 Ipsenol: 1H-1H COSY.

5.5 Caryophyllene Oxide.

5.6 13C-13C Correlations: Inadequate.

5.7 Lactose.

5.8 Relayed Coherence Transfer: TOCSY.

5.9 HMQC – TOCSY.

5.10 ROESY.

5.11 VGSE.

5.12 Gradient Field NMR.

Chapter 6. NMR Spectrometry of Other Important Spin 1/2 Nuclei.

6.1 Introduction.

6.2 15N Nuclear Magnetic Resonance.

6.3 19F Nuclear Magnetic Resonance.

6.4 29Si Nuclear Magnetic Resonance.

6.5 31P Nuclear Magnetic Resonance.

6.6 Conclusion.

Chapter 7. Solved Problems.

7.1 Introduction.

Chapter 8. Assigned Problems.

8.1 Introduction.

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