Catalytic Asymmetric Synthesis / Edition 3

Catalytic Asymmetric Synthesis / Edition 3

by Iwao Ojima
     
 

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ISBN-10: 047017577X

ISBN-13: 9780470175774

Pub. Date: 03/08/2010

Publisher: Wiley

Since this important work was first published in 1993, the field of catalytic asymmetric synthesis has grown explosively, spawning effective new methods for obtaining enantiomerically pure compounds on a large scale and stimulating new applications in diverse fields-from medicine to materials science. Catalytic Asymmetric Synthesis, Third Edition addresses these

Overview

Since this important work was first published in 1993, the field of catalytic asymmetric synthesis has grown explosively, spawning effective new methods for obtaining enantiomerically pure compounds on a large scale and stimulating new applications in diverse fields-from medicine to materials science. Catalytic Asymmetric Synthesis, Third Edition addresses these rapid changes through contributions from highly recognized world leaders in the field.

This seminal text presents detailed accounts of the most important catalytic asymmetric reactions known today, and discusses recent advances and essential information on the initial development of certain processes. An excellent working resource for academic researchers and industrial chemists alike, the Third Edition features:

Six entirely new chapters focusing on novel approaches to catalytic asymmetric synthesis including non-conventional media/conditions, organocatalysis, chiral Lewis and Bronsted acids, CH activation, carbon-heteroatom bond-forming reactions, and enzyme-catalyzed asymmetric synthesis

A new section focusing on the important new reaction, asymmetric metathesis, in carbon-carbon bound-forming reactions

Updated chapters on hydrogenation, carbon-carbon bond-forming reactions, hydrosilylations, carbonylations, oxidations, amplifications and autocatalysis, and polymerization reactions

Retaining the best of its predecessors but now thoroughly up to date, Catalytic Retaining Synthesis, Third Edition serves as an excellent desktop reference and text for researchers and students from the upper-level undergraduates through experienced professionals in industry or academia.

Product Details

ISBN-13:
9780470175774
Publisher:
Wiley
Publication date:
03/08/2010
Edition description:
New Edition
Pages:
998
Product dimensions:
6.40(w) x 9.30(h) x 2.00(d)

Table of Contents

Preface ix

Preface to the Second Edition xi

Preface to the First Edition xiii

Contributors xv

1 Catalytic Asymmetric Synthesis in Nonconventional Media/Conditions Chikako Ogawa Sh&ubar; Kobayashi 1

2 Asymmetric Organocatalysis 37

2A Enantioselective Organocatalysis Involving Iminium, Enamine, SOMO, and Photoredox Activation Allan J. B. Watson David W. C. MacMillan 39

21 Asymmetric Acid-Base Bifunctional Catalysis with Organic Molecules Yi Wang Li Deng 59

2C Asymmetric Phase-Transfer and Ion Pair Catalysis Seiji Shirakawa Keiji Maruoka 95

3 Chiral Lewis Acids and Brønsted Acids in Asymmetric Synthesis Hisashi Yamamoto Cheol Hong Cheon 119

4 Asymmetric Synthesis through C-H Activation Huw M. L. Davies Jørn Hansen 163

5 Asymmetric Carbon-Heteroatom Bond-Forming Reactions Yoshiji Takemoto Hideto Miyabe 227

6 Enzyme-Catalyzed Asymmetric Synthesis Harald Gröger 269

7 Transition Metal-Catalyzed Homogeneous Asymmetric Hydrogenation Gao Shang Wei Li Xumu Zhang 343

8 Asymmetric Carbon-Carbon Bond-Forming Reactions 437

8A Catalytic Asymmetric Conjugate Addition Jian-Xin Ji Albert S. C. Chan 439

8B Enantioselective Allylic Substitutions with Carbon Nucleophiles Günter Helmchen Uli Kazmaier Sebastian Förster 497

8C Asymmetric Carbometallation and Carbocyclizations Iwao Ojima Joseph J. Kaloko Stephen J. Chaterpaul Yu-Han Gary Teng Chi-Feng Lin 643

8D Asymmetric Ene Reactions and Cycloadditions Koichi Mikami Kohsuke Aikawa 683

8E Catalytic Enantioselective Olefin Metathesis Reactions Amir H. Hoveyda Steven J. Malcolmson Simon J. Meek Adil R. Zhugralin 739

9 Asymmetric Hydrosilylation of Carbon-Carbon Double Bonds and Related Reactions Jin Wook Han Tamio Hayashi 771

10 Asymmetric Carbonylations Cyril Godard Aurora Ruiz Montserrat Diéguez Oscar Pàmies Carmen Claver 799

11 Asymmetric Oxidations and Related Reactions Kazuhiro Matsumoto Tsutomu Katsuki 839

12 Asymmetric Amplification and Autocatalysis Kenso Soai Tsuneomi Kawasaki Takanori Shibata 891

13 Asymmetric Polymerization Shingo Ito Kyoko Nozaki 931

Index 987

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