Chemical Reactor Analysis and Design / Edition 3

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This is the Third Edition of the standard text on chemical reaction engineering, beginning with basic definitions and fundamental principles and continuing all the way to practical applications, emphasising real-world aspects of industrial practice. The two main sections cover applied or engineering kinetics, reactor analysis and design. Includes updated coverage of computer modeling methods and many new worked examples. Most of the examples use real kinetic data from processes of industrial importance.

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Product Details

  • ISBN-13: 9780470565414
  • Publisher: Wiley
  • Publication date: 8/16/2010
  • Edition description: New Edition
  • Edition number: 3
  • Pages: 900
  • Product dimensions: 8.20 (w) x 10.00 (h) x 1.40 (d)

Table of Contents

Chapter 1: Elements of Reaction Kinetics.

1.1 Definitions of Chemical Rates.

1.2 Rate Equations.

1.3 Coupled Reactions.

1.4 Reducing the Size of Kinetic Models.

1.5 Bio-Kinetics.

1.6 Complex Reactions.

1.7 Modeling the Rate Coefficient.

Chapter 2: Kinetics of Heterogeneous CatalyticReactions.

2.1 Introduction.

2.2 Adsorption on Solid Catalysts.

2.3 Rate Equations.

2.4 Complex Catalytic Reactions.

2.5 Experimental Reactors.

2.6 Model Discrimination and Parameter Estimation.

2.7 Sequential Design of Experiments.

2.8 Expert Systems in Kinetics Studies.

Chapter 3: Transport Processes with Reactions Catalyzed bySolids.

Part One Interfacial Gradient Effects.

3.1 Reaction of a component of a fluid at the surface of asolid.

3.2 Mass and heat transfer resistances.

3.3 Concentration or partial pressure and temperaturedifferences.

Part Two Intraparticle Gradient Effects.

3.4 Molecular-, Knudsen-, and surface diffusion in pores.

3.5 Diffusion in a catalyst particle.

3.6 Diffusion and reaction in a catalyst particle. A continuummodel.

3.7 Falsification of rate coefficient and activation energy bydiffusion limitations.

3.8 Influence of diffusion limitations on the selectivities ofcoupled reactions.

3.9 Criteria for the importance of intraparticle diffusionlimitations.

3.10 Multiplicity of steady states in catalyst particles.

3.11 Combination of external and internal diffusionlimitations.

3.12 Diagnostic experimental criteria for the absence ofinternal and external mass transfer limitations.

3.13 Nonisothermal particles.

Chapter 4: Noncatalytic Gas-Solid Reactions.

4.1 A Qualitative Discussion of Gas-Solid Reactions.

4.2 General Model with Interfacial and IntraparticleGradients.

4.3 Heterogeneous Model with Shrinking Unreacted Core.

4.4 Models Accounting Explicitly for the Structure of theSolid.

4.5 On the Use of More Complex Kinetic Equations.

Chapter 5: Catalyst Deactivation.

5.1 Types of Catalyst Deactivation.

5.2 Kinetics of Catalyst Poisoning.

5.3 Kinetics of Catalyst Deactivation by Coke Formation.

Chapter 6: Gas-Liquid Reactions.

6.1 Introduction.

6.2 Models for Transfer at a Gas-Liquid Interface.

6.3 Two-Film Theory.

6.4 Surface Renewal Theory.

6.5 Experimental Determination of the Kinetics of Gas-LiquidReactions.

Chapter 7: The Modeling of Chemical Reactors.

7.1 Approach.

7.2 Aspects of Mass-, Heat- and Momentum Balances.

7.3 The Fundamental Model Equations.

Chapter 8: The Batch and Semibatch Reactors.


8.1 The Isothermal Batch Reactor.

8.2 The Nonisothermal Batch Reactor.

8.3 Semibatch Reactor Modeling.

8.4 Optimal Operation Policies and Control Strategies.

Chapter 9: The Plug Flow Reactor.

9.1 The Continuity, Energy, and Momentum Equations.

9.2 Kinetic Studies Using a Tubular Reactor with Plug Flow.

9.3 Design and Simulation of Tubular Reactors with PlugFlow.

Chapter 10: The Perfectly Mixed Flow Reactor.

10.1 Introduction.

10.2 Mass and Energy Balances .

10.3 Design for Optimum Selectivity in SimultaneousReactions.

10.4 Stability of Operation and Transient Behavior.

Chapter 11: Fixed Bed Catalytic Reactors.

Part One Introduction.

11.1 The Importance and Scale of Fixed Bed CatalyticProcesses.

11.2 Factors of Progress: Technological Innovations andIncreased Fundamental Insight.

11.3 Factors Involved in the Preliminary Design of Fixed BedReactors.

11.4 Modeling of Fixed Bed Reactors.

Part Two Pseudohomogeneous Models.

11.5 The Basic One-Dimensional Model.

11.6 One-Dimensional Model with Axial Mixing.

11.7 Two-Dimensional Pseudohomogeneous Models.

Part Three Heteorgeneous Models.

11.8 One-Dimensional Model Accounting for InterfacialGradients.

11.9 One-Dimensional Model Accounting for Interfacial andIntraparticle Gradients.

11.10 Two-Dimensional Heterogeneous Models.

Chapter 12: Complex Flow Patterns.

12.1 Introduction.

12.2 Macro- and Micro-Mixing in Reactors.

12.3 Models Explicitly Accounting for Mixing.

12.4 Micro- Probability Density Function Methods.

12.5 Micro-PDF Moment Methods: Computational Fluid Dynamics.

12.6 Macro-PDF / Residence Time Distribution Methods.

12.7 Semi-Empirical Models for Reactors with Complex FlowPatterns.

Chapter 13: Fluidized Bed and Transport Reactors.

13.1 Introduction.

13.2 Technological Aspects of Fluidized Bed and RiserReactors.

13.3 Some Features of the Fluidization and Transport ofSolids.

13.4 Heat Transfert in Fluidized Beds.

13.5 Modeling of Fluidized Bed Reactors.

13.6 Modeling of a Transport of Riser Reactor.

13.7 Fluidized Bed Reactor Models Considering Detailed FlowPatterns.

13.8 Catalytic Cracking of Vacuum Gas Oil.

Chapter 14:Multiphase Flow Reactors.

14.1 Types of Multiphase Flow Reactors.

14.2 Design Models for Multiphase Flow Reactors.

14.3 Specific Design Aspects.

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  • Anonymous

    Posted August 10, 2005

    Thoroughly Mediocre

    There aren't many textbook selections out there for professors of graduate reaction engineering, so I guess that's why some choose this book. This book reads like it's a compilation of individual papers from the authors, wrapped up and called a textbook. There is essentially no flow between chapters (not to mention an inconsistent font throughout the book). Another side effect of the paper-compilation method is the extensive amount of referencing done. This is OK in an academic periodical, but I expect a little more explanation from a textbook. Another gripe I have is that when going through some calculation techniques, huge (very important) steps will be glossed over and unexplained. There is a lot covered in this book. I would never recommend this book for an undergraduate class, however, I can understand why some professors choose it at the graduate level (We'll leave out the fact that my professor was buddy-buddy with one of the authors . . .).

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