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Diffusion in Natural Porous Media: Contaminant Transport, Sorption/Desorption and Dissolution Kinetics
     

Diffusion in Natural Porous Media: Contaminant Transport, Sorption/Desorption and Dissolution Kinetics

by Peter Grathwohl
 

Diffusion in Natural Porous Media: Contaminant Transport, Sorption/Desorption and Dissolution Kinetics introduces the general principles of diffusion in the subsurface environment and discusses the implications for the fate and transport of contaminants in soils and groundwater. Emphasis is placed on sorption/desorption and the dissolution kinetics of organic

Overview

Diffusion in Natural Porous Media: Contaminant Transport, Sorption/Desorption and Dissolution Kinetics introduces the general principles of diffusion in the subsurface environment and discusses the implications for the fate and transport of contaminants in soils and groundwater. Emphasis is placed on sorption/desorption and the dissolution kinetics of organic contaminants, both of which are limited by the slow speed of molecular diffusion.
Diffusion in Natural Porous Media: Contaminant Transport, Sorption/Desorption and Dissolution Kinetics compiles methods for calculating the diffusion coefficients of organic compounds (in aqueous solution or vapor phase) in natural porous media. The author uses analytical solutions of Fick's 2nd law and some simple numerical models to model diffusive transport under various initial and boundary conditions. A number of these models may be solved using spreadsheets.
The book examines sorption/desorption rates of organic compounds in various soils and aquifer materials, and also examines the dissolution kinetics of nonaqueous phase liquids in aquifers, in both the trapped residual phase and in pools.
Diffusion in Natural Porous Media: Contaminant Transport, Sorption/Desorption and Dissolution Kinetics concludes with a discussion of the impact of slow diffusion processes on soil and groundwater decontamination and the implications of these processes for groundwater risk assessment.

Editorial Reviews

From the Publisher
'... this book forms a very useful reference for data on diffusion parameters and also on methdology for quantifying contaminant transport related to diffusional processes.'
Episodes, 22:4 (1999)
Booknews
Launches a series that intends to deal with topics as varied as atmospheric dynamics, coastal oceanography, subsurface flow and transport, lava flow, oil spills on the sea surface, indoor contamination and clean-room technology, risk assessment, data acquisition, and stochastic models. Introduces the general principles of diffusion in the subsurface environment and discusses the implications for the fate and transport of contaminants in the soils and groundwater. Emphasizes sorption and desorption and the dissolution kinetics of organic contaminants, both of which are limited by the slow speed of molecular diffusion. Also compiles methods for calculating the diffusion coefficients of organic compounds in aqueous solution or vapor phase through natural porous media. Annotation c. by Book News, Inc., Portland, Or.

Product Details

ISBN-13:
9781461376026
Publisher:
Springer US
Publication date:
04/30/2013
Series:
Topics in Environmental Fluid Mechanics Series , #1
Edition description:
Softcover reprint of the original 1st ed. 1998
Pages:
207
Product dimensions:
6.10(w) x 9.25(h) x 0.02(d)

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