Electroanalytical Chemistry

Electroanalytical Chemistry

by Allen J. Bard
     
 

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ISBN-10: 0824776089

ISBN-13: 9780824776084

Pub. Date: 08/28/1986

Publisher: Taylor & Francis

This volume is part of a continuing series designed to provide authoritative reviews on recent developments and applications of well-established techniques in the field of modern electroanalytical chemistry. Offering in-depth discussions of areas under current investigation, it also covers techniques generally outside the scope of electroanalytical chemistry which can

Overview

This volume is part of a continuing series designed to provide authoritative reviews on recent developments and applications of well-established techniques in the field of modern electroanalytical chemistry. Offering in-depth discussions of areas under current investigation, it also covers techniques generally outside the scope of electroanalytical chemistry which can be fruitfully applied to electrochemical problems.

Electroanalytical and other chemists are concerned not only with the application of new and classical methods of solving analytical problems, but also with the fundamental principles upon which these techniques are based. As electroanalytical techniques prove increasingly useful in such diverse areas as electro-organic synthesis, fuel cell studies, and radical ion formation -- as well as in solving problems dealing with the kinetics and mechanisms of electrode reactions and the effects of electrode surface phenomena, adsorption, and the electrical double layer on electrode reactions -- the value of these techniques becomes ever more apparent.

Electroanalytical Chemistry: A Series of Advances, Volume 14 is essential for the specialist and nonspecialist alike -- it provides a background and a starting point for graduate students undertaking research in these areas, and is of special interest to practicing analytical chemists concerned with electroanalytical techniques.

Product Details

ISBN-13:
9780824776084
Publisher:
Taylor & Francis
Publication date:
08/28/1986
Series:
Electroanalytical Chemistry: A Series of Advances Series, #14
Pages:
464
Product dimensions:
6.25(w) x 9.25(h) x 0.25(d)

Table of Contents

Introduction to the Seriesiii
Contributors to Volume 14v
Contents of Other Volumesix
Precision in Linear Sweep and Cyclic Voltammetry1
I.Introduction2
II.Electrode Mechanism Analysis3
III.Measurement Precision12
IV.Derivative Cyclic Voltammetry28
V.Linear Sweep Voltammetry57
VI.Normalized Potential Sweep Voltammetry65
VII.Linear Current Potential (LCP) Analysis82
VIII.Reaction Order Approach86
IX.More Recent Developments99
X.Conclusions108
Acknowledgments108
References108
Conformational Change and Isomerization Associated with Electrode Reactions113
I.Introduction114
II.Theoretical Consideration115
III.Conformational Change That Precedes Electron Transfer123
IV.Conformational Change or Isomerization That Follows Electron Transfer138
V.Conformational Changes That Are Concurrent with Electron Transfer189
Summary200
References201
Square-Wave Voltammetry209
I.Introduction209
II.Definition of Square-Wave Voltammetry212
III.Theory of Square-Wave Voltammetry215
IV.Experimental Square-Wave Voltammetry259
V.Conclusions301
Acknowledgments303
References303
Infrared Vibrational Spectroscopy of the Electron-Solution Interface309
I.Introduction310
II.Theory and Methodology312
III.Applications343
IV.Conclusions and Future Directions422
V.Appendix: The Laws of Reflection and Fresnel's Equations423
Acknowledgment434
References434
Author Index441
Subject Index455

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