Heterogeneous and Liquid Phase Processes: Laboratory Studies Related to Aerosols and Clouds / Edition 1

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Overview

The "European Experiment on the Transport and Transformation of Environmentally Relevant Trace Constituents over Europe" (EUROTRAC) was established in 1986 to tackle the scientific problem and combine the expertise, knowledge and resources in Europe, in order to apply them over a large region covering the greater part of the continent. EUROTRAC is a coordinated multidisciplinary scientific research project involving field measurements, laboratory studies, instrument development and development of comprehensive computer models for the simulation of the physical and chemical processes in the lower atmosphere.
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Product Details

Table of Contents

Highlights of the Results 1
Original Aims of the EUROTRAC Subproject HALIPP 4
Review of the Activities and Achievement of the EUROTRAC Subproject HALIPP 7
Individual Reports from HALIPP Contributors
Kinetic Investigation of the Stability of Peroxonitric Acid and its Reaction with SulfurIV in Aqueous Solution 77
Electrolyte Effects on Aqueous Oxidation of Sulfur Dioxide by Strong Oxidants 89
Metal Ion Catalysed Autoxidation of Dissolved Sulfur Dioxide 97
Catalytic Effects of Atmospheric Aerosol Particles in the Aqueous Phase of Trace Gases 105
Kinetics of Ozonation Processes in Cloud and Fog Water: Effect of Transition Metal Ions on Free Radical Reactions 110
Kinetics of SIV Oxidation in Aqueous Solution: Impact of Transition Metal Ion Transformations 116
The Interaction of SO[subscript x] and NO[subscript y] Species in Aqueous Solution: Photo and Metal Ion Catalysis 126
Kinetics and Mechanisms of Acid Generation in Clouds and Precipitation 133
Chain Oxidation Mechanisms of SIV in Aqueous Solution: Application of Radical Scavenger Techniques 140
Formation and Reaction of Oxidants in the Aqueous Phase 146
Photocatalysis of Tropospheric Chemistry by Sea Spray 153
Phase Partitioning and Redox Processes in Fog and Cloud Systems 163
Gas - Liquid Interactions 175
Laboratory Determination of Physico-chemical Rate Parameters Pertinent to Mass Transfer into Cloud and Fog Droplets 182
Determination of [beta]-Pinene OH Radical Rate Constant - Possible Impact of Solid Particles 191
Calorimetric Study of Lewis Acid Centres and Adsorbed Water in the Heterogeneous Reactions Involving Tropospheric Particles 197
Laboratory Studies of the Phototransformation of Organic Compounds in the Presence of Water and/or Inorganic Particulate Solids 205
Heterogeneous Reactions of Nitrogen Oxides [actual symbol not reproducible] with Surfaces Representative of Atmospheric Aerosol 213
Heterogeneous Reactions of Air Pollutants on Various Solid Surfaces 221
HALIPP Publications 1988-1995 227
Subject Index 251
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