Innovations in Chemical Biology / Edition 1

Innovations in Chemical Biology / Edition 1

by Bilge Sener

The growing role of chemistry and the contribution of chemical and pharmaceutical industries to the science of mankind are enermously going on. The system for training researchers in the various areas of chemistry has maintained a largely traditional and single disciplinary focus. Although many investigators have broadened their selection of research techniques at

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The growing role of chemistry and the contribution of chemical and pharmaceutical industries to the science of mankind are enermously going on. The system for training researchers in the various areas of chemistry has maintained a largely traditional and single disciplinary focus. Although many investigators have broadened their selection of research techniques at the level of organized and integrated programs. Chemical Biology is one of the fastest areas of science as a multidisciplinary during this century. The interdisciplinary study of molecules in living systems at a health science campus helps to integrate the traditional disciplines of chemistry and biology by understanding the molecular mechanisms of biological processes provides an oppotunity to manipulate them in a defined and predictable way. The next century will witness more tremendous achievements of chemistry as well as its application of different fields for the benefit of mankind life in terms of healthy, good, productive and comfortable long life. This book will be an excellent issue for a rich scientific diversity in the field of Chemistry and Biology. The focus of this book is on chemical and molecular aspects of Chemical Biology. The interpretation of chemistry for biology is probably slightly broader than what commonly is referred to as Chemical Biology, thus also including topis related to molecular biology, biochemistry, ecology, semiochemicals, environmental and material sciences. There are a number of chapters including analytical chemistry, biochemical technology, bioinformatics, catalysis and nanotechnology, carbohydrate chemistry, bioorganic and bioinorganic chemistry that are of interest to chemical biologists. Eurasia conference is one of the dreams for realizing the development of chemical sciences in Asia with the coopeartion of European countries initiated by Prof. Dr. Hitoshi Ohtaki. Therefore, this book belonged to the Proceedings of the 9th

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Springer Netherlands
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9.21(w) x 6.14(h) x 1.06(d)

Table of Contents

Foreword v

Preface vii

Memorial Tribute to Professor Dr. Hitoshi Ohtaki ix

Contributors xxxv

1 Development of Chemistry in Asia with the Cooperation of European Countries Hitoshi Ohtaki 1

2 Functional Peptidomics: Recent Developments and State of Art Vadim T. Ivanov E. Yu. Blishchenko Andrey A. Karelin 15

3 Structural Bioinformatics in the Discovery of Novel Drugs Mahmud Tareq Hassan Khan Ingebrigt Sylte 29

4 Chemical and Biological Studies with an Aconitum and a Delphinium Species Ayhan Ulubelen Ufak Kolak 39

5 Novel Bioactive Natural Products from Marine and Terrestrial Sources Athar Ata 51

6 Bioactive Turkish Plant Extracts and Their Constituents Gulacti Topcu Gulendam Tumen Turgut Kilic Ahmet C. Goren Asli Barla Zeynep Turkmen David G. I. Kingston 61

7 Chamomile Biodiversity of the Essential Oil Qualitative-Quantitative Characteristics Ivan Salamon 83

8 Recent Progress on Bioactivity Studies on Turkish Lycopodium clavatum L. Ilkay Orhan Bilge Sener 91

9 Separation and Characterization of the Vanillin Compound from Soda Lignin Mohamad Nasir Mohamad Ibrahim M. Y. Nor Nadiah M. S. Norliyana S. Shuib 103

10 Recent Development of Ring Closing Metathesis Approach to Bioactive Heterocycles: Synthesis of Nakadomarin A, Quinolines, and Indoles Masako Nakagawa Mitsuhiro Arisawa Atsushi Nishida 111

11 Effect of Molecular Structure on Polymorphic Nucleation of BPT Derivatives Mitsutaka Kitamura Takayuki Hara 121

12 The Golden Ratio in the Creations of Nature Arises in the Architecture of Atoms and Ions Raji Heyrovska 133

13 Interaction of Thioamides, Selenoamides and Amides with Di-iodine: A Study of the Mechanism of Action of Anti-thyroid Drugs SotirisK. Hadjikakou Nick Hadjiliadis 141

14 Catalytic Properties of Polyamido Dendrimers Metin Tulu Mehmet Senel 151

15 Swell Ratio Parameter for Prediction of Chemically Crosslinked Low Density Polyethylene Foam Expansion Characteristics Coswald Stephan Sipaut Geoff L. A. Sims 161

16 Ruthenium Tris-bypyridine/Zeolite-Y/Titanium Dioxide Nano-Assembly: 'Ship-in-a-Bottle' Synthesis and Application in Heterogeneous Photodegradation of 2,4-xylidine Leon M. Jr. Payawan Eva Marie Ratilla Stefan Bossmann 171

17 Infrared Spectroelectrochemical Analysis of the Binuclear Rhenium Complex of the Form, [Re(CO) subscript 3 Cl subscript 2](tpbq) Arnie R. de Leon Girlie Naomi N. Sison Stacey J. Borg 175

18 Microbial Synthesis of Poly (3-Hydroxybutyrate-co-4-Hydroxybutyrate) by Cupriavidus sp. USMAA1020 Isolated from Malaysian Environment Amirul A. Abdullah Ahmad R. M. Yahya Kumar Sudesh Mohd N. M. Azizan Mohd I. A. Majid 187

19 Rust Phase Transformation in the Presence of Mangrove Tannins Afidah A. Rahim Noor Hamdah Musa Rohana Adnan M. Jain Kassim E. Rocca J. Steinmetz 197

20 Treatment of Oil-Water Mixture Using Illite Clay Mineral Fatma Turak Huseyin Afsar 205

21 Removal of Catechol and Resorcinol from Aqueous Solutions by Adsorption onto High Area Activated Carbon Cloth Numan Hoda Edip Bayram Erol Ayranci 213

22 Removal of Metobromuron Pesticide from Aqueous Solutions by Adsorption at High Area Activated Carbon Cloth Numan Hoda Edip Bayram Erol Ayranci 225

23 Effects of Thermal Treatment and Storage on Hydroxymethylfurfural (HMF) Content and Diastase Activity of Honeys Collected from Middle Anatolia in Turkey Kadir Turhan 233

24 The Degradation Kinetics of Phenol Solutions with Ozone Kadir Turhan Suheyla Uzman 241

25 Determination of Some Trace Metals in Edible Mushrooms Samples Using Atomic Absorption Spectrometry Kadir Turhan 247

26 Sorption of Zn(II) and Pb(II) Ions by a New Resin Synthesized from Sumac Tannin and Gelatin Kadir Turhan Fatma Turak Mahmure Ustun Ozgur 253

27 In Quest of Friedly Free Radicals: Reactions of Iodine Atom Free Radicals with Some Biologically Important Compounds M. Mohammad A. Dar Sajid Jahangir I. A. Tahiri M. S. Subhani K. M. Khan 261

28 Adsorption of Cu(II) from Aqueous Solutions by Sumac (Rhus coriaia L.) Tannins Ahmet Lutfi Ugur Mahmure Ustun Ozgur Gulsah Gumrukcu 269

29 Sorption of Pb(II) and Zn(II) Ions from Aqueous Solution by Tannin Resins Fatma Turak Kadir Turhan Mahmure Ustun Ozgur 277

30 Determination of Ibuprofen, Pseudoephedrine HCl, Chlorpheniramine Maleate and Nipagen by Liquid Chromatography and Fractional Factorial Design Burge Asci Ozlem Aksu Donmez Abdurrezzak Bozdogan Sidika Sungur 285

31 Comparison of Derivative Spectrophotometry and Partial Least Squares (PLS-1) Calibration for the Determination of Caffeine in Energy Drinks Ozlem Aksu Donmez Mahmure Ustun Ozgur Abdurrezzak Bozdogan 291

32 Simultaneous Spectrophotometric Determination of Food Additives (Benzoic Acid, Caffeine, Aspartame and Acesulfame-K) in Cola Drinks by PLS Multivariate Calibration Method Fatma Turak Mahmure Ustun Ozgur Abdurrezzak Bozdogan 299

33 PLS-UV Spectrophotometric Method for the Simultaneous Determination of Ternary Mixture of Sweeteners (Aspartame, Acesulfame-K and Saccharin) in Commercial Products Fatma Turak Mahmure Ustun Ozgur Abdurrezak Bozdogan 305

34 Factorial Design in the Optimization of Preconcentration Procedure for Aluminum Determination by AAS Sule Dinc Abdurrezak Bozdogan Guzin Alpdogan Burge Asci Sidika Sungur 313

35 Oxidation of L-asorbic Acid in Copper(II) Ion-Catalyzed Polyvinylpyrrolidone Solutions Serkan Angi Hasan Kilic Filiz Imer 319

36 A Potentiometric Investigation of Primary Amines in Non-adqueous Media Feray Aydogan Sevgi Kocaoba Huseyin Afsar 327

37 Domino-Heck Type Reactions of N-Benzoyl-2-Azabicyclo[2.2.1]Hept-5-ene-3-one Cigdem Yolacan Nuket Ocal Dieter E. Kaufmann 331

38 Synthesis of Different Epibatidine Analogues with Domino- and Reductive Heck Reactions Emine Bagdatli Nuket Ocal 337

39 Synthesis of 2,4-Disubstituted-3,4-Dihydro-2H-Naphth[2,1-e 1,3]Oxazines Zuhal Turgut Emel Pelit Kadir Turhan 343

40 Chemical Constituents of Salvia frigida Boiss Mehmet Disbudak Umit Salan 347

41 Protease Inhibition and Antioxidant Actions of Some Aqueous Allium Extracts Eugenia Teodor Wanda Buzgariu Alexandrina Rugina Mirela Diaconu G.L. Radu 353

42 Synthesis and Characterization of Novel Zn(II) Dimeric Phthalocyanines Saziye Abdurrahmanoglu Mustafa Bulut Ozer Bekaroglu 361

43 Synthesis and Characterization of N-[1,10-Phenanthroline]-N'-[(Benzo-15-Crown-5)yl] Thiourea and Its Complex with Copper(I) Fikriye Tuncel Elmali Ulvi Avciata Nebahat Demirhan Ahmet Gul 367

44 Synthesis and Characterization of New Type Soluble Porphyrazine Containing 1-Bromo-3-Methylbutan Group and Investigation of Its Complexes Ali Erdogmus Gulnur Keser Karaoglan Ulvi Avciata Ahmet Gul 375

45 Synthesis and Characterization of New Type Soluble Porphyrazine Containing 3-Phenylpropyl Bromide Group and Investigation of Its Complexes Ali Erdogmus Ulvi Avciata Ahmet Gul 383

46 Synthesis and Characterization of Novel Peripherally 3-Bromo-1-Phenyl-1-Propene Derivative of Porphyrazine Bahadir Keskin Ulvi Avciata Ahmet Gul 389

47 Lacunarity Analysis of TEM Images of Heat-Treated Hybrid Organosilica Materials Raymond V. Rivera-Virtudazo Alvin Karlo G. Tapia Jesus Felix B. Valenzuela Leonard Dela Cruz Herman D. Mendoza Emily Valentin Castriciones 397

48 The Mechanical Properties of Water-Based Emulsion Polymers: Effect of Reaction Conditions Ayfer Sarac Kadir Turhan 405

49 Investigation of Spectrophotometrical and Fluorescent Behavior of 1,3-Diethyl-5-(Quinoline-2-Ylmethylene)-2-Thioxodihydropyrimidine-4,6(1H,5H)-Dione in Various Solvents Mevlude Canlica H. Kerim Beker Ibrahim E. Ozyigit Alper Akinci Seniz Kaban 411

Annex 421

Index 423

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