Inorganic Fluorine Chemistry: Toward the 21st Century

Inorganic Fluorine Chemistry: Toward the 21st Century

by Joseph S. Thrasher, Steven H. Strauss
     
 

Offers an up-to-date account of fundamental and applied research and points to future directions in inorganic fluorine chemistry. Reviews the major advances in fluorine-containing substituent groups. Provides a critical examination of coordination numbers greater than six among fluorides and oxofluorides. Discusses attempts to control chemical reactivity and

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Overview

Offers an up-to-date account of fundamental and applied research and points to future directions in inorganic fluorine chemistry. Reviews the major advances in fluorine-containing substituent groups. Provides a critical examination of coordination numbers greater than six among fluorides and oxofluorides. Discusses attempts to control chemical reactivity and stability through the use of more nucleophilic sources of fluoride or, conversely, more weakly coordinating anions. Features chapters on new fluorine-containing ligands in organometallic, transition metal, solid state, lanthanide and actinide chemistry.

Product Details

ISBN-13:
9780841228696
Publisher:
American Chemical Society
Publication date:
03/28/1998
Series:
ACS Symposium Series, #555
Pages:
497
Product dimensions:
9.00(w) x 5.80(h) x 1.10(d)

Table of Contents

Inorganic Fluorine Chemistry: Toward the 21st Century, J.S. Thrasher and S.H. Strauss
Thermodynamic Aspects of the Remarkable Oxidizing Capabilities of Fluorine-Lewis-Fluoroacid Mixtures, C. Shen, R. Hagiwara, T. E. Mallouk, and N. Bartlett
Photochemical and Thermal Dissociation Synthesis of Krypton Difluoride, S.A. Kinkead, J.R. FitzPatrick, J. Foropoulos Jr., R.J. Kissane, and J.D. Purson
Main-Group Fluorides with Coordination Numbers Greater than Six, K. Seppelt
Heptacoordinated Main-Group Fluorides and Oxofluorides, K.O. Christe, E.C. Curtis, D.A. Dixon, H.P.A. Mercier, J.C. P. Sanders, G.J. Schrobilgen, and W.W. Wilson
Monofluoroxenonium Hexafluorometalates XeF]+MF[6[- (M = As or Sb): A Course to Different Onium Cations, R. Minkwitz and B. Bäck
Influence of Fluorine and Parahalogen Substituents on the Chemistry of Some Functional Groups, A. Hass and A. Brosius
Functionalization of Pentafluoro-*l]6-sulfanyl (SF[5) Olefins and Acetylenes, R. Winter and G. L. Gard
Fluoro-Sulfur Anions: Transition States, Intermediates, and Reagents, R. Mews
Quest for an Aromatic Silicon Species: An Unusual Geometry around Silicon in a 10-Si-5 Siliconate, S. K. Chopra, C. D. Moon, and J.C. Martin
Reaction of SiH[4 with UF[6 and HF below 25°C: Fourier Transform IR Study, W.V. Cicha, J.H. Wang, and J. Covey
Fluorinated Aldehydes and Their Polymers, W. B. Farnham and S. G. Zane
Synthesis and Chemistry of Perfluoro Macrocycles: Perfluoro Crown Ethers and Cryptands, R. J. Lagow, T.-Y. Lin, H. W. Roesky, W.D. Clark, W.-H. Lin, J.S. Brodbelt, S.D. Maleknia, and C.C. Liou
Alkali Metal Polyhydrogen Fluorides: Useful Halogen-Exchanges Media, R.E. Fernandez and J. S. Thrasher
New and Revisited Transition Metal Chemistry of Fluoro-olefins and Fluorodienes, R.P. Hughes, O.J. Curnow, P.R. Rose, X. Zheng, E.N. Mairs, and A. L. Rheingold
Organometallic Chemistry of Fluorinated Isocyanides, D. Lentz
Synthetic, Structural and Reactivity Studies of Organocobalt(III) Compounds Containing Fluorinated Alkyl Ligands, P.J. Toscano., E. Barren, H. Brand, L. Konieczny, E.J. Schermerhorn, K. Shufon, and S. van Winkler
Perfluorovinyl and Perfluoroaryl Zinc and Cadmium Reagents: Preparation, Stability, and Reactivity, D.J. Burton
Organic and Main-Group Chemistry of the 2,4,6-Tris(trifluoromethyl)phenyl Substituent: Kinetic Stabilization through Steric and Electronic Effects, F.T. Edelmann
Reaction of Nonmetal Fluorides with Some Platinum Metal Complexes, R.W. Cockman, E.A.V. Ebsworth, J. H. Holloway, H. Murdoch, N. Robertson, and P.G. Watson
Large Polyfluorinated Anions Used To Generate Coordinative Unsaturation in Cations, P.K. Hurlburt, D.M. Van Seggen, J.J. Rack and S.H. Strauss
Stabilization of Unusual Cations by Very Weakly Basic Fluoro Anions, F. Aubke
Synthesis, Structure, and Reactivity of Highly Soluble Organotitanium Lewis Acids, C.H. Winter and X.-X. Zhou
New Synthetic Routes to Cyclopentadienyluranium(IV) Fluorides: Redox and Atom-Abstraction Reactions, M. Weydert and R.A. Andersen
Activation of Carbon-Fluorine Bonds by Oxidative Addition to Low-Valent Transition Metals, C.E. Osterberg and T. G. Richmond
Recent Developments in the Chemistry of Fluorinated Isopropoxides and Tertiary Butoxides, A.P. Purdy and C.F. George
(Fluoroaklyl)phosphine Coordination Chemistry, D.M. Roddick and R. C. Schnabel

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