Ionic Liquids As Green Solvents: Progress and Prospects

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Overview

Following Ionic Liquids: Industrial Applications to Green Chemistry, SS #818, by the same editors, this book focuses on exciting new developments in ionic liquids.

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Product Details

  • ISBN-13: 9780841238565
  • Publisher: American Chemical Society
  • Publication date: 9/25/2003
  • Series: ACS Symposium Series, #856
  • Pages: 616
  • Product dimensions: 9.10 (w) x 6.10 (h) x 1.30 (d)

Meet the Author

University of Alabama

Queen's University of Belfast

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Table of Contents

Preface
Overview
1. Selection of Ionic Liquids for Green Chemical Applications, John D. Holbrey, Megan B. Turner, and Robin D. Rogers
2. Ionic Liquids: Improved Syntheses and New Products, Adrian J. Carmichael, Maggrel Deetlefs, Martyn J. Earle, Ute Fröhlich, and Kenneth R. Seddon
3. Challenges to the Commercial Production of Ionic Liquids, Philip E. Rakita
4. Industrial Preparation of the Phosphonium Ionic Liquids, Christine J. Bradaric, Andrew Downard, Christine Kennedy, Allan J. Robertson, and Yuehui Zhou
5. New Ionic Liquids Based on Alkylsulfate and Alkyl Oligoether Sulfate Anions: Synthesis and Applications, Peter Wasserscheid, Roy van Hal, Andreas Bösmann, Jochen
6. E*ber, and Andreas Jess Green Synthesis of Ionic Liquids for Green Chemistry, Rex X. Ren
7. Expeditious Synthesis of Ionic Liquids Using Ultrasound and Microwave Irradiation, Rajender S. Varma
8. Unprecedented Synthesis of 1,3-dialkylimidazolium-2-carboxylate: Applications in the Synthesis of Halogen-Free Ionic Liquids and Reactivity as Carbon Dioxide Transfer Agent to Active C-H Bonds, M. Aresta, I. Tkatchenko, and I. Tommasi
9. Commercially Available Salts as Building Blocks for New Ionic Liquids, James H. Davis, Jr. and Philip A. Fox
Characterization and Engineering
10. Phase Equilibria of Gases and Liquids with 1-n-butyl-3-Methylimidazolium Tetrafluroborate, Jennifer L. Anthony, Jacob M. Crosthwaite, Daniel G. hert, Sudhir N.V.K. Aki, Edward J. Maginn, and Joan f. Brennecke
11. Heat Capacities of Ionic Liquids and Their Applications as Thermal Fluids, John D. Holbrey, W. Matthew Reichert, Ramana G. Reddy, and Robin D. Rogers
12. Thermodynamic Properties of Liquid Mixtures Containing Ionic Liquids, Andreas Heintz, Jochen K. Lehmann, and Sergey P. Verekin
13. Liquid and Solid-State Structures of 1,3-Dimenthylimidazolium Salts, D.T. Bowron, C. Hardacre, J.D. Holbrey, S.E.J. McMath, M. Nieuwenhuyzen, and A.K. Soper
14. Molecular Structure of Various Ionic Liquids from Gas Phase Ab Initio Calculations, Timothy I. Morrow and Edward J. Maginn
15. Transition Structure Models of Organic Reactions in Chloroaluminate Ionic Liquids: Cyclopentadiene and Methyl Acrylate Diels-Alder Reaction in Acidic and Basic Melts of 1-Ethyl-3-methylimidazolium Chloride with Aluminum(III) Chloride, Orlando Acevedo and Jeffrey D. Evanseck
16. Biotransformations in Ionic Liquids: An Overview, Roger A. Sheldon, F. van Rantwijk, and R. Madeira Lau
17. Enzymatic Condensation Reactions in Ionic Liquids, Nicole Kaftzik, Sebastian Neumann, Maria-Regina Kula, and Udo Kragl
18. Aspects of Chemical Recognition and Biosolvation within Room Temperature Ionic Liquids, Gary A. Baker, Sheila N. Baker, T. Mark McClesky, and James H. Werner
19. Ionic Liquids Create New Opportunities for Nonaqueous Biocatalysis with polar Substrates: Acylation of Glucose and Ascorbic Acid
20. Enzymatic Catalysis in Ionic Liquids and Supercritical Carbon Dioxide, Pedro Lozano, Teresa De Diego, Daniel Carrié, Michael Vaultier, and José L. Iborra
21. Efficient Lipase-Catalyzed Enantioselective Acylation in an Ionic Liquid Solvent System, Toshiyuki Itoh, Yoshihito Nishimura, Masaya Kashiwagi, and Makoto Onaka
Non-Catalytic and Catalytic Chemistry
22. Acids and Bases in Ionic Liquids, Douglas R. MacFarlane and Stewart A. Forsyth
23. Catalytic Olefin Epoxidation and Dihydroxylation with Hydrogen Peroxide in Common Ionic Liquids: Comparative Kinetics and Mechanistic Study, Mahdi M. Abu-Omar, Gregory S. Owens, and Armando Durazo
24. Polarity Variation of Room Temperature Ionic Liquids and Its Influence on a Diels-Alder Reaction, Richard A. Bartsch and Sergei V. Dzyuba
25. Polar, Non-Coordinating Ionic Liquids as Solvents for Coordination Polymerization of Olefins, Kevin H. Shaughnessy, marc A. Klingshirn, Steven J. P'Pool, John D. Holbrey, and Robin D. Rogers
26. The Importance of Hydrogen Bonding to Catalysis in Ionic Liquids: Inhibition of Allylic Substitution and Isomerization by [bmim][BF[4], James Ross and Jianliang Xiao
27. Recent Developments in the Use of N -Heterocyclic Carbenes: Applications in Catalysis, Rebecca M. Kissling, Mihai S. Viciu, Gabriela A. Grasa, Romain F. Germaneau, Tatyana Güveli, Marie-Christine Pasareanu, Oscar Navarro-Fernandez, and Steven P. Nolan
Photochemistry
28. An Overview of Photochemistry in Ionic Liquids, Richard M. Pagni
29. Diffusion-Controlled Reactions in Room Temperature Ionic Liquids, Charles M. Gordon, ANdrew J. McLean, Mark J. Muldoon, and Ian R. Dunkin
30. Amine Mediated Photoreduction of Aryl Ketones in N -Heterocyclic Ionic Liquids: Novel Solvent Effects Leading to Altered Product Distribution, Paul B. Jones, John L. Reynolds, Robert G. Brinson, and Ryan L. Butke
31. Radiation Chemistry of Ionic Liquids: Reactivity of Primary Species, James F. Wishart
32. Pulse Radioanalysis Studies of Reaction Kinetics in Ionic Liquids, P. neta, D. Behar, and J. Grodkowski
33. Organic Electrochemistry in Ionic Liquids, Andrew P. Doherty and Claudine A. Brooks
34. Solvent-Solute Interactions in Ionic Liquid Media: Electrochemical Studies of the Ferricenium-Ferrocene Couple, M. Cristina Lagunas, William R. Pitner, Jan_Albert van der Berg, and Kenneth R. Seddon
35. Electrochemical Studies of Ambient Temperature Ionic Liquids Based on Choline Chloride, Andrew P. Abbott, Glen Capper, David L. Davies, Helen Munro, Raymond K. Rasheed, and Vasuki Tambyrajah
36. Electrodeposition of Nanoscale Metals and Semiconductors from Ionic Liquids, Sherif Zein El Abedin and Frank Endres
Novel Applications
37. Plasticizing Effects of Imidazolium Salts in PMMA: High-Temperature Stable Flexible Engineering Materials, Mark P. Scott, Michael G. Benton, Mustafizur Rahman, and Christopher S. Brazel
38. The Use of Ionic Liquids in Polymer Gel Electrolytes, Hugh C. De Long, Paul C. Trulove, and Thomas E. Sutto
39. Electrochemistry: Ionic Liquid Electroprocessing of Reactive Metals, Jianming Lu and David Dreisinger
40. Electrochemistry: Electrochemically Generated Superoxide Ion in Ionic Liquids: Applications to Green Chemistry, I.M. AlNashef, M.A. Matthews, and J.W. Weidner
41. Conventional Aspects of Unconventional Solvents: Room Temperature Ionic Liquids as Ion-Exchangers and Ionic Surfactants, Mark L. Dietz, Julie A. Dzielawa, Mark P. Jensen, and Millicent A. Firestone
42. Extraction of Chlorophenols from Water Using Room Temperature Ionic Liquids, Evangelina Bekou, Dionysios D. Dionysiou, Ru-Ying Qian, and Gregory D. Botsaris
Indices
Author Index
Subject Index

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