Ionic Liquids As Green Solvents: Progress and Prospects

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Overview


Following Ionic Liquids: Industrial Applications to Green Chemistry, SS #818, by the same editors, this book focuses on exciting new developments in ionic liquids.
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Product Details

  • ISBN-13: 9780841238565
  • Publisher: American Chemical Society
  • Publication date: 9/25/2003
  • Series: ACS Symposium Series , #856
  • Pages: 616
  • Product dimensions: 9.10 (w) x 6.10 (h) x 1.30 (d)

Meet the Author

University of Alabama

Queen's University of Belfast

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Table of Contents

Preface
1 Selection of Ionic Liquids for Green Chemical Applications 2
2 Ionic Liquids: Improved Syntheses and New Products 14
3 Challenges to the Commercial Production of Ionic Liquids 32
4 Industrial Preparation of Phosphonium Ionic Liquids 41
5 New Ionic Liquids Based on Alkylsulfate and Alkyl Oligoether Sulfate Anions: Synthesis and Applications 57
6 Green Synthesis of Ionic Liquids for Green Chemistry 70
7 Expeditions Synthesis of Ionic Liquids Using Ultrasound and Microwave Irradiation 82
8 Unprecedented Synthesis of 1,3-dialkylimidazolium-2-carboxylate: Applications in the Synthesis of Halogen-Free Ionic Liquids and Reactivity as Carbon Dioxide Transfer Agent to Active C-H Bonds 93
9 Commercially Available Salts as Building Blocks for New Ionic Liquids 100
10 Phase Equilibria of Gases and Liquids with 1-n-butyl-3-Methylimidazolium Tetrafluoroborate 110
11 Heat Capacities of Ionic Liquids and Their Applications as Thermal Fluids 121
12 Thermodynamic Properties of Liquid Mixtures Containing Ionic Liquids 134
13 Liquid and Solid-State Structures of 1,3-Dimethylimidazolium Salts 151
14 Molecular Structure of Various Ionic Liquids from Gas Phase Ab Initio Calculations 162
15 Transition Structure Models of Organic Reactions in Chloroaluminate Ionic Liquids: Cyclopentadiene and Methyl Acrylate Diels-Alder Reaction in Acidic and Basic Melts of 1-Ethyl-3-methylimidazolium Chloride with Aluminum(III) Chloride 174
16 Biotransformations in Ionic Liquids: An Overview 192
17 Enzymatic Condensation Reactions in Ionic Liquids 206
18 Aspects of Chemical Recognition and Biosolvation within Room Temperature Ionic Liquids 212
19 Ionic Liquids Create New Opportunities for Nonaqueous Biocatalysis with Polar Substrates: Acylation of Glucose and Ascorbic Acid 225
20 Enzymatic Catalysis in Ionic Liquids and Supercritical Carbon Dioxide 239
21 Efficient Lipase-Catalyzed Enantioselective Acylation in an Ionic Liquid Solvent System 251
22 Acids and Bases in Ionic Liquids 264
23 Catalytic Olefin Epoxidation and Dihydroxylation with Hydrogen Peroxide in Common Ionic Liquids: Comparative Kinetics and Mechanistic Study 277
24 Polarity Variation of Room Temperature Ionic Liquids and Its Influence on a Diels-Alder Reaction 289
25 Polar, Non-Coordinating Ionic Liquids as Solvents for Coordination Polymerization of Olefins 300
26 The Importance of Hydrogen Bonding to Catalysis in Ionic Liquids: Inhibition of Allylic Substitution and Isomerization by [bmim] [BF[subscript 4]] 314
27 Recent Developments in the Use of N-Heterocyclic Carbenas: Applications in Catalysis 323
28 An Overview of Photochemistry in Ionic Liquids 344
29 Diffusion-Controlled Reactions in Room Temperature Ionic Liquids 357
30 Amine Mediated Photoreduction of Aryl Ketones in N-Heterocyclic Ionic Liquids: Novel Solvent Effects Leading to Altered Product Distribution 370
31 Radiation Chemistry of Ionic Liquids: Reactivity of Primary Species 381
32 Pulse Radiolysis Studies of Reaction Kinetics of Ionic Liquids 397
33 Organic Electrochemistry in Ionic Liquids 410
34 Solvent-Solute Interactions in Ionic Liquid Media: Electrochemical Studies of the Ferricenium-Ferrocene Couple 421
35 Electrochemical Studies of Ambient Temperature Ionic Liquids Based on Choline Chloride 439
36 Electrodeposition of Nanoscale Metals and Semiconductors from Ionic Liquids 453
37 Plasticizing Effects of Imidazolium Salts in PMMA: High-Temperature Stable Flexible Engineering Materials 468
38 The Use of Ionic Liquids in Polymer Gel Electrolytes 478
39 Electrochemistry: Ionic Liquid Electroprocessing of Reactive Metals 495
40 Electrochemistry: Electrochemically Generated Superoxide Ion in Ionic Liquids: Applications to Green Chemistry 509
41 Conventional Aspects of Unconventional Solvents: Room Temperature Ionic Liquids as Ion-Exchangers and Ionic Surfactants 526
42 Extraction of Chlorophenols from Water Using Room Temperature Ionic Liquids 544
Author Index 563
Subject Index 565
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