Mass Spectrometry of Inorganic and Organometallic Compounds: Tools - Techniques - Tips / Edition 1

Paperback (Print)
Used and New from Other Sellers
Used and New from Other Sellers
from $62.10
Usually ships in 1-2 business days
(Save 17%)
Other sellers (Paperback)
  • All (4) from $62.10   
  • New (1) from $62.10   
  • Used (3) from $88.74   

Overview

This is the first modern book to treat inorganic and organometallic mass spectrometry simultaneously. It is textbook and handbook in one; as a textbook it introduces the techniques and gives hints on how to apply the various techniques, as a handbook it lists all available ionization techniques for just about any given compound. The book also includes non-mathematical explanations of how modern MS instruments work

Mass Spectrometry of Inorganic and Organometallic Compounds will inspire the synthetic inorganic and organometallic chemist with the confidence to apply some of the new techniques to their characterization problems.

Read More Show Less

Product Details

Table of Contents

Preface.

List of commonly-used abbreviations.

Chapter 1 Fundamentals.

1.1 Introduction.

1.2 Inlets.

1.3 Collision-induced dissociation.

1.4 Detectors.

1.5 Mass resolution.

1.6 Data processing.

1.7 Isotopes.

References.

Chapter 2 Mass analysers.

2.1 Introduction.

2.2 Sectors.

2.3 Quadrupoles.

2.4 Quadrupole Ion Trap.

2.5 Time-of-flight.

2.6 Fourier Transform Ion Cyclotron Resonance.

References.

Chapter 3 Ionisation techniques.

3.1 Introduction.

3.2 Electron ionisation.

3.3 Chemical Ionisation.

3.4 Field ionisation / Field desorption.

3.5 Plasma Desorption.

3.6 Fast Atom Bombardment / Liquid Secondary Ion Mass Spectrometry.

3.7 Matrix Assisted Laser Desorption Ionisation.

3.8 Inductively Coupled Plasma Mass Spectrometry.

3.9 Electrospray ionisation.

References.

Chapter 4 The ESI MS behaviour of simple inorganic compounds.

4.1 Introduction.

4.2 Simple metal salts.

4.3 Polyanions formed by main group elements.

4.4 Oxoanions formed by main group elements.

4.5 Borane anions.

4.6 Fullerenes.

4.7 Inorganic phosphorus compounds: phosphoranes and cyclophosphazenes.

4.8 Summary.

References.

Chapter 5 The ESI MS behaviour of coordination complexes.

5.1 Introduction.

5.2 Charged, "simple" coordination complexes.

5.3 (Neutral) metal halide coordination complexes.

5.4 Metal complexes of polydentate oxygen donor ligands: polyethers, crown ethers, cryptands and calixarenes.

5.5 Porphyrins and metalloporphyrins.

5.6 Metal alkoxides – highly moisture-sensitive coordination compounds.

5.7 b-Diketonate complexes.

5.8 Metal complexes of carbohydrates.

5.9 Metal complexes of amino acids, peptides and proteins.

5.10 Oxoanions, polyoxoanions and related species.

5.11 Metal clusters.

5.12 Compounds with anionic sulfur and selenium donor ligands.

5.13 Characterisation of metal-based anticancer drugs, their reaction products and metabolites.

5.14 In situ formation of coordination complexes as an ionisation technique.

5.15 Summary.

References.

Chapter 6 The ESI MS behaviour of main group organometallic compounds.

6.1 Introduction.

6.2 Organometallic derivatives of group 14 elements.

6.3 Organometallic derivatives of group 15 elements.

6.4 Organometallic derivatives of group 16 elements; organo-sulfur, -selenium and -tellurium compounds.

6.5 Organomercury compounds.

6.6 Other organometallic derivatives.

6.7 Summary.

References.

Chapter 7 The ESI MS behaviour of transition metal and lanthanide organometallic compounds.

7.1 Introduction.

7.2 Metal carbonyl complexes.

7.3 Metal isocyanide complexes.

7.4 Metal cyclopentadienyl and related complexes.

7.5 Metal h3-allyl complexes.

7.6 Metal arene complexes.

7.7 Formation of p-hydrocarbon complexes and their use as an ionisation aid.

7.8 Metal-acetylene/acetylide complexes, and complexes of metal-acetylides.

7.9 Transition metal s-alkyl and aryl complexes.

7.10 Mass spectrometry of lanthanide organometallic complexes.

7.11 Summary.

References.

Chapter 8 A selection of special topics.

8.1 Introduction.

8.2 The characterisation of dendrimers using ESI and MALDI–TOF MS techniques.

8.3 Investigating the formation of supramolecular coordination assemblies using ESI MS.

8.4 Using ESI MS as a tool for directing chemical synthesis: A case studyinvolving the platinum metalloligands [Pt2(m–E)2(PPh3)4] (E = S, Se).

8.5 Applications of ESI MS in the detection of reactive intermediates and catalyst screening.

References.

Appendix 1 Naturally occurring isotopes.

Appendix 2 Periodic table of the elements.

Appendix 3 Alphabetical list of elements.

Appendix 4 Mass Spectrometry Glossary of Terms.

Appendix 5 Useful sources of information on mass spectrometry.

Read More Show Less

Customer Reviews

Be the first to write a review
( 0 )
Rating Distribution

5 Star

(0)

4 Star

(0)

3 Star

(0)

2 Star

(0)

1 Star

(0)

Your Rating:

Your Name: Create a Pen Name or

Barnes & Noble.com Review Rules

Our reader reviews allow you to share your comments on titles you liked, or didn't, with others. By submitting an online review, you are representing to Barnes & Noble.com that all information contained in your review is original and accurate in all respects, and that the submission of such content by you and the posting of such content by Barnes & Noble.com does not and will not violate the rights of any third party. Please follow the rules below to help ensure that your review can be posted.

Reviews by Our Customers Under the Age of 13

We highly value and respect everyone's opinion concerning the titles we offer. However, we cannot allow persons under the age of 13 to have accounts at BN.com or to post customer reviews. Please see our Terms of Use for more details.

What to exclude from your review:

Please do not write about reviews, commentary, or information posted on the product page. If you see any errors in the information on the product page, please send us an email.

Reviews should not contain any of the following:

  • - HTML tags, profanity, obscenities, vulgarities, or comments that defame anyone
  • - Time-sensitive information such as tour dates, signings, lectures, etc.
  • - Single-word reviews. Other people will read your review to discover why you liked or didn't like the title. Be descriptive.
  • - Comments focusing on the author or that may ruin the ending for others
  • - Phone numbers, addresses, URLs
  • - Pricing and availability information or alternative ordering information
  • - Advertisements or commercial solicitation

Reminder:

  • - By submitting a review, you grant to Barnes & Noble.com and its sublicensees the royalty-free, perpetual, irrevocable right and license to use the review in accordance with the Barnes & Noble.com Terms of Use.
  • - Barnes & Noble.com reserves the right not to post any review -- particularly those that do not follow the terms and conditions of these Rules. Barnes & Noble.com also reserves the right to remove any review at any time without notice.
  • - See Terms of Use for other conditions and disclaimers.
Search for Products You'd Like to Recommend

Recommend other products that relate to your review. Just search for them below and share!

Create a Pen Name

Your Pen Name is your unique identity on BN.com. It will appear on the reviews you write and other website activities. Your Pen Name cannot be edited, changed or deleted once submitted.

 
Your Pen Name can be any combination of alphanumeric characters (plus - and _), and must be at least two characters long.

Continue Anonymously

    If you find inappropriate content, please report it to Barnes & Noble
    Why is this product inappropriate?
    Comments (optional)