Metastable Liquids: Concepts and Principles

Metastable Liquids: Concepts and Principles

by Pablo G. Debenedetti
     
 

ISBN-10: 0691085951

ISBN-13: 9780691085951

Pub. Date: 12/23/1996

Publisher: Princeton University Press

Metastable Liquids provides a comprehensive treatment of the properties of liquids under conditions where the stable state is a vapor, a solid, or a liquid mixture of different composition. It examines the fundamental principles that govern the equilibrium properties, stability, relaxation mechanisms, and relaxation rates of metastable liquids. Building on

Overview

Metastable Liquids provides a comprehensive treatment of the properties of liquids under conditions where the stable state is a vapor, a solid, or a liquid mixture of different composition. It examines the fundamental principles that govern the equilibrium properties, stability, relaxation mechanisms, and relaxation rates of metastable liquids. Building on the interplay of kinetics and thermodynamics that determines the thermophysical properties and structural relaxation of metastable liquids, it offers an in-depth treatment of thermodynamic stability theory, the statistical mechanics of metastability, nucleation, spinodal decomposition, supercooled liquids, and the glass transition.

Both traditional topics—such as stability theory—and modern developments—including modern theories of nucleation and the properties of supercooled and glassy water—are treated in detail. An introductory chapter illustrates, with numerous examples, the importance and ubiquity of metastable liquids. Examples include the ascent of sap in plants, the strategies adopted by many living organisms to survive prolonged exposure to sub-freezing conditions, the behavior of proteins at low temperatures, metastability in mineral inclusions, ozone depletion, the preservation and storage of labile biochemicals, and the prevention of natural gas clathrate hydrate formation. All mathematical symbols are defined in the text and key equations are clearly explained. More complex mathematical explanations are available in the appendixes.

Product Details

ISBN-13:
9780691085951
Publisher:
Princeton University Press
Publication date:
12/23/1996
Series:
Physical Chemistry: Science and Engineering Series
Edition description:
New Edition
Pages:
400
Product dimensions:
6.40(w) x 9.30(h) x 1.20(d)

Table of Contents

Preface and Acknowledgments
1Introduction: Metastable Liquids in Nature and Technology1
2Thermodynamics63
3Kinetics147
4Supercooled Liquids235
5Outlook363
App. 1Stability of Fluids: Thermodynamic and Mathematical Proofs367
App. 2Thermodynamics of Fluid Interfaces377
App. 3Definitions of Microscopic and Statistical Quantities389
Index397

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