Table of Contents
Introduction 1
The Flashcard App 3
1 Getting Started in Chemical Calculations 5
How to Study Chemistry 6
The Macroscopic and Microscopic Levels of Chemistry 7
Units of Measurement (SI System) 8
Significant Figures 10
Problem Solving by the Unit Conversion Method 11
2 Atoms, Ions, and Molecules 23
The Subatomic Particles 24
Elements 25
The Periodic Table 25
Chemical Formulas: Ions and Molecules 27
Naming Compounds 29
3 Moles, Stoichiometry, and Equations 45
Balancing Chemical Equations 46
Avogadro's Number and Molar Mass 48
Moles and Stoichiometry 49
Limiting Reactant and Percent Yield 51
Percent Composition and Empirical Formulas 53
Confronting Mole Problems 55
4 Aqueous Solutions 65
Molarity (M) 66
Solubility and Precipitation 66
Acids, Bases, and Neutralization 69
Oxidation-Reduction 71
Net Ionic Equations 74
Titrations 88
5 Gases and Gas Laws 99
Gas Laws (P, V, n, and T) 100
Gas Stoichiometry 104
The Kinetic-Molecular Theory of Gases 106
Nonideal Gases 108
Working Gas Law Problems 109
6 Thermochemistry 117
Energy and Reactions 118
Enthalpy (ΔH) 122
Hess's Law 123
Calorimetry 125
7 Electrons and Quantum Theory 131
Light and Matter 132
Bohr's Model 134
Quantum Mechanics 135
Quantum Numbers and Orbitals 135
Electron Configuration 138
Working Matter and Light Problems 144
8 Periodic Trends 147
Periodic Table Revisited 148
Ionization Energy 149
Electron Affinity 151
Periodic Trends 152
9 Lewis Structures and Chemical Bonding 157
Lewis Symbols 158
Electronegativity 160
Ionic Bonds and Lattice Energy 161
Covalent Bonds 163
Resonance 166
Bond Energy and Bond Length 167
More About Lewis Structures 168
10 Molecular Geometry and Hybridization 177
Molecular Geometry (VSEPR) 178
Valence Bond Theory (Hybridization) 181
Molecular Orbital (MO) Theory 184
Molecular Geometry Revisited 186
11 Solids, Liquids, and Intermolecular Forces 189
Types of Intermolecular Forces 190
Properties of Liquids 193
Solids 195
Phase Changes 196
12 Solutions 207
Concentration Units 208
Temperature and Pressure Effects on Solubility 214
Colligative Properties 214
Colloids 218
Colligative Properties Problems 218
15 Kinetics 227
Reaction Rates 228
Rate Laws 230
Integrated Rate Laws (Time and Concentration) 233
Arrhenius and Activation Energy 236
Catalysis 239
Mechanisms 240
More About Rate Law and Half-Life (t1/2) 242
14 Chemical Equilibria 247
Equilibrium 248
Equilibrium Constants [K] 249
Le Chatelier's Principle 250
Additional Equilibria Problems 253
15 Acids and Bases 265
Brønsted-Lowry Acids and Bases 266
Strength of Acids and Bases 267
Kw-the Water Dissociation Constant 268
pH 269
Acid-Base Equilibrium [Ka and Kb) 271
Acid-Base Properties of Salts and Oxides 273
Lewis Acids and Bases 274
Working Weak Acid and Base Problems 275
16 Buffers and Additional Equilibria 283
The Common Ion Effect 284
Buffers and pH 284
Titrations and Indicators 287
Solubility Equilibria (Ksp) 288
Kl-Complex Ion Equilibria 291
pH and Titrations Problems 291
17 Entropy and Free Energy 305
The Three Laws of Thermodynamics 306
Entropy 307
Gibbs Free Energy 307
Free Energy and Reactions 308
Working Thermodynamic Problems 309
18 Electrochemistry 319
Redox Reactions 320
Galvanic (Voltaic) Cells 322
Standard Reduction Potentials (E°) 325
Nernst Equation 329
Electrolytic Cells 330
Electrolysis 332
19 Chemistry of the Elements 339
Hydrogen 340
General Properties of Metals 341
Band Theory of Conductivity 341
Periodic Trends in Metallic Properties 342
General Properties of Nonmetals 343
Periodic Trends of Nonmetals 344
Properties of the Transition Metals 344
Coordination Compounds: Crystal Field Theory 345
Complex Ions 346
20 Nuclear Chemistry 349
Nuclear Reactions 350
Nuclear Stability 353
Half-Lives (t1/2) 355
Mass/Energy Conversions 358
Fission and Fusion 359
Nuclear Decay 360
21 Organic Chemistry, Biochemistry, and Polymers 367
Organic Compounds 368
Hydrocarbons and Nomenclature 368
Functional Groups 374
Polymers 375
Proteins 378
Carbohydrates 378
Nucleic Acids 380
Organic Reactions Problems 380
Answer Key 391
Periodic Table of the Elements 444