Organoboranes for Syntheses

Organoboranes for Syntheses

by P. V. Ramachandran
     
 

This book examines the recent advances in the art of organic synthesis via organoboranes. The volume includes a wide range of topics in asymmetric synthesis, such as reduction,
aldol reaction, allyboration, homologation, and cyclopropanation. Additional subjects include Suzuki coupling, amino acid synthesis, fluoro-organic synthesis,
boron catalysts for… See more details below

Overview

This book examines the recent advances in the art of organic synthesis via organoboranes. The volume includes a wide range of topics in asymmetric synthesis, such as reduction,
aldol reaction, allyboration, homologation, and cyclopropanation. Additional subjects include Suzuki coupling, amino acid synthesis, fluoro-organic synthesis,
boron catalysts for stereoselective transformations,
heterocyclic synthesis and novel borohydride reagents.

Product Details

ISBN-13:
9780841237087
Publisher:
American Chemical Society
Publication date:
03/28/2001
Series:
ACS Symposium Series, #783
Pages:
264
Product dimensions:
5.90(w) x 8.80(h) x 0.80(d)

Table of Contents

Preface
1Recent Advances in Borane Chemistry1
2Lithium Aminoborohydrides: Reagents with Multiple Personalities18
3New Stereoselective Transformations Involving Organoboranes and Organozinc Compounds: Applications of the Boron-Zinc Chain Reaction and the Diastereoselective Migration of Organoboranes33
4Synthesis and Cyclizations of Conjugated Systems Derived from Organoboranes52
5New Organic Synthetic Methods Using the NaBH[subscript 4]/I[subscript 2] System65
6Cross-Coupling Reaction of Organoboron Compounds with Organic Electrophiles80
7Rhodium-Catalyzed Addition Reactions of Organoboronic Acids84
8Arylboron Catalysts for Stereoselective Organic Transformations108
9Asymmetric Reduction of [alpha]-Functionalized Ketones with Organoboron-Based Chiral Reducing Agents122
10Enantioselective Cyclopropanation Using Dioxaborolane Ligands136
11Organoboron Chemistry on Alumina: The Suzuki Reaction148
12Synthesis of Heterocyclic Compounds by Allylboration Reactions160
13Novel Silyl-Mediated 10-TMS-9-BBD Organoborane Reagents for Asymmetric Synthesis176
14Asymmetric Aldol Reactions Using Boron Enolates: Applications to Polyketide Synthesis195
15Recent Progress in Asymmetric Synthesis with Boronic Esters207
16Syntheses of Chiral Lactones via Asymmetric Allylboration220
Author Index235
Subject Index236

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