The Organometallic Chemistry of the Transition Metals / Edition 2

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Overview

Fully updated and expanded to reflect recent advances, this Fifth Edition of the classic text provides students and professional chemists with a comprehensive introduction to the principles and general properties of organometallic compounds, as well as including practical information on reaction mechanisms and detailed descriptions of contemporary applications. With increased focus on organic synthesis applications, nanoparticle science, and green chemistry, the Fifth Edition brings this vital resource up to date.
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Editorial Reviews

SciTech Book News
...provides an introduction to the principles and general properties of organometallic compounds...supplies practical information about reaction mechanisms...
Choice
Each edition of this organometallics book...keeps getting better...useful as a reference...useful for undergraduate and graduate students.
Choice
Each edition of this organometallics book...keeps getting better...useful as a reference...useful for undergraduate and graduate students.
SciTech Book News
...provides an introduction to the principles and general properties of organometallic compounds...supplies practical information about reaction mechanisms...
Booknews
This text and reference book provides an introduction to the principles and general properties of organometallic compounds. It also supplies practical information about reaction mechanisms, along with descriptions of contemporary applications to organic synthesis, organized by reaction type. References to pertinent literature are featured throughout. This edition includes new sections on coupling reactions, C-F bond activation, giant molecules, paramagnetic organometallics, and surface organometallic chemistry, as well as updated information on metal alkyls, aryls, hydrides, metallocene polymerization, and o-bonded ligands. Crabtree teaches chemistry at Yale University. Annotation c. Book News, Inc., Portland, OR (booknews.com)
From the Publisher
"At the same time, that same model guarantees that it will still be one of the primary choices of the next generation of organometallic chemists and readers with interests in organometallic chemistry. " (ACS' Organometallics Journal, 1 December 2010)
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Product Details

  • ISBN-13: 9780471592402
  • Publisher: Wiley, John & Sons, Incorporated
  • Publication date: 3/28/1994
  • Edition description: Older Edition
  • Edition number: 2
  • Pages: 512
  • Product dimensions: 6.45 (w) x 9.53 (h) x 1.13 (d)

Meet the Author

Robert H. Crabtree, PhD, is a professor in the Department of Chemistry at Yale University.

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Table of Contents

1 Introduction 1
2 General properties of organometallic complexes 29
3 Metal alkyls, aryls, and hydrides and related [sigma]-bonded ligands 53
4 Carbonyls, phosphine complexes, and ligand substitution reactions 87
5 Complexes of [pi]-bound ligands 125
6 Oxidative addition and reductive elimination 159
7 Insertion and elimination 183
8 Nucleophilic and electrophilic addition and abstraction 207
9 Homogeneous catalysis 235
10 Physical methods in organometallic chemistry 275
11 Metal-ligand multiple bonds 309
12 Applications of organometallic chemistry 343
13 Clusters and the metal-metal bond 379
14 Applications to organic synthesis 417
15 Paramagnetic, high-oxidation-state, and high-coordination-number complexes 463
16 Bioorganometallic chemistry 491
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