Reactive Intermediate Chemistry / Edition 1

Reactive Intermediate Chemistry / Edition 1

5.0 1
by Robert A. Moss
     
 

ISBN-10: 0471233242

ISBN-13: 9780471233244

Pub. Date: 01/09/2004

Publisher: Wiley

Reactive intermediates (the chemical intermediates present during a reaction) offer an explanation for why reactions proceed, or don't proceed, and why reactions occur quickly or slowly. This book provides a greater understanding of chemical behavior, and enables chemists to design new reactions for a variety of purposes (pharmaceuticals, fine chemicals,

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Overview

Reactive intermediates (the chemical intermediates present during a reaction) offer an explanation for why reactions proceed, or don't proceed, and why reactions occur quickly or slowly. This book provides a greater understanding of chemical behavior, and enables chemists to design new reactions for a variety of purposes (pharmaceuticals, fine chemicals, biotechnological, agricultural, etc.). Among other features, this authoritative volume is: Edited and authored by world-renowned leaders in physical organic chemistry. Ideal for use as a primary or supplemental graduate textbook for reactive intermediates in organic, inorganic, and physical chemistry Also features a discussion section with integrated computational studies in every chapter

Product Details

ISBN-13:
9780471233244
Publisher:
Wiley
Publication date:
01/09/2004
Edition description:
New Edition
Pages:
1084
Product dimensions:
6.36(w) x 9.47(h) x 2.16(d)

Table of Contents

Preface..

PART 1: REACTIVE INTERMEDIATES.

1. Carbocations (R.A. McClelland).

2. Crossing the Borderline Between SN1 and SN2 Nucleophilic Substitution at Aliphatic Carbon(T.L. Amyes, et al.).

3. Carbanions (S. Gronert).

4. Radicals (M. Newcomb).

5. Non-Kekul Molecules as Reactive Intermediates (J.A. Berson).

6. Organic Radical Ions (H.D. Roth).

7. Singlet Carbenes (M. Jones Jr. and R.A. Moss).

8. Stable Singlet Carbenes (G. Bertrand).

9. Triplet Carbenes (H. Tomioka).

10. Atomic Carbon (P.B. Shevlin).

11. Nitrenes (M.S. Platz).

12. Synthetic Carbene and Nitrene Chemistry (M.P. Doyle).

13. Nitrenium Ions (D.E. Falvey).

14. Silylenes (W. Ando and N. Tokitoh).

15. Strained Hydrocarbons: Structures, Stability, and Reactivity (K.B. Wiberg).

16. Arynes (M. Winkler, et al.).

PART 2: METHODS AND TEMPORAL REGIMES.

17. Matrix Isolation (T. Bally).

18. Nanosecond Laser Flash Photolysis: A Tool for Physica l Organic Chemistry (J.C. Scaiano).

19. The Picosecond Realm (E. Hilinski).

20. Reactions on the Femtosecond Time Scale (J.E. Baldwin).

21. Potential Energy Surfaces and Reaction Dynamics (B.K. Carpenter).

22. The Partnership Between Electronic Structure Calculations and Experiments in the Study of Reactive Intermediates (W.T. Borden).

Index.

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