Reactive Intermediate Chemistry / Edition 1

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Overview

Reactive intermediates (the chemical intermediates present during a reaction) offer an explanation for why reactions proceed, or don't proceed, and why reactions occur quickly or slowly. This book provides a greater understanding of chemical behavior, and enables chemists to design new reactions for a variety of purposes (pharmaceuticals, fine chemicals, biotechnological, agricultural, etc.). Among other features, this authoritative volume is: Edited and authored by world-renowned leaders in physical organic chemistry. Ideal for use as a primary or supplemental graduate textbook for reactive intermediates in organic, inorganic, and physical chemistry Also features a discussion section with integrated computational studies in every chapter

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Editorial Reviews

From the Publisher
...impressive reference...would be invaluable to anyscientist whose project it is to understand the degradation pathwayof a new chemical entity." (Pharmaceutical Development &Technology, February 2005)

"This is truly an excellent book. The editors…have areputation as gifted scientific writers…the graphics are alsoexcellent, with a common format used throughout the entire book."(Journal of the American Chemical Society, August 18,2004)

"…this is a very nice book, which is an absolute must forevery chemist concerned with reactive intermediates.”(Angewandte Chemie International Edition, August 6,2004)

"This book, which is well-organized and contains an extensiveindex, would be an indispensable resource for graduate students andprofessionals in academia or industry.” (E-STREAMS,July 2004)

"An excellent and up-to-date resource for graduate students andpracticing organic chemists. Highly recommended." (Choice,June 2004, Vol. 41 No. 10)

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Product Details

  • ISBN-13: 9780471233244
  • Publisher: Wiley
  • Publication date: 1/9/2004
  • Edition description: New Edition
  • Edition number: 1
  • Pages: 1084
  • Product dimensions: 6.36 (w) x 9.47 (h) x 2.16 (d)

Meet the Author

Robert A. Moss is the Louis P. Hammett Professor ofChemistry at Rutgers, the State University of New Jersey, NewBrunswick, NJ. He received his Ph. D. with Professor Gerhard Closs(Chicago) and was a postdoctoral student with Professor RonaldBreslow (Columbia). Dr. Moss has been an A.P. Sloan FoundationFellow, and a visiting professor or scientist at M.I.T., theUniversity of Oxford, the Politechnika (Warsaw), the WeizmannInstitute, the National Research Council of Canada, and the HebrewUniversity of Jerusalem. He has more than 350 scientificpublications in the areas of reactive intermediates and chemistryin molecular aggregates.

Matthew S. Platz was born in New York City and graduatedfrom the State University of NY at Albany ( B.Sc. in Chemistry andMathematics) in 1973 and obtained his Ph.D. in Chemistry studyingwith Professor Jerome Berson in 1976. After a postdoctoral stintwith Professor Gerhard Closs, Platz joined the faculty of The OhioState University in 1978 where he has spent his entire independentcareer. Platz served as chair of the OSU Chemistry Department from1994-1999, was the Melvin S. Newman Professor (1994-2001), and wasnamed Distinguished University Professor in 2001. Platz has been aSloan Fellow, a Camille and Henry Dreyfus Teacher-Scholar, and aCope Scholar of the American Chemical Society. He has over 200scientific publications and holds over a dozen patents.

Maitland Jones, Jr. turned to chemistry only after theinvention of the curveball by his peers made it clear that he wouldnever be a major league centerfielder. He received his B.S. degreefrom Yale College and his M. S. and Ph. D. degrees from YaleUniversity, where he studied with William von E. Doering. After apostdoctoral year with Jerry Berson at Wisconsin he came toPrinceton in 1964 as an Instructor. He has been there ever since,and is now David B. Jones Professor of Chemistry. He has been avisiting professor at Columbia and Harvard in this country, as wellas at the Vrije Universiteit in Holland, the Kiev Polytechnic inUkraine, and Fudan University in the People's Republic of China. Herecently spent three months in Basel as the Freiwillige AkademischeGesellschaft Professor. He and his wife, the artist Susan Hockaday,were comasters of Stevenson Hall, one of Princeton's undergraduatecolleges, for several years. Together with the members of hisresearch group, he has published more than 200 papers centered onthe chemistry of reactive intermediates, as well as a recenttextbook on organic chemistry.

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Table of Contents

Preface..

PART 1: REACTIVE INTERMEDIATES.

1. Carbocations (R.A. McClelland).

2. Crossing the Borderline Between SN1 and SN2 NucleophilicSubstitution at Aliphatic Carbon(T.L. Amyes, et al.).

3. Carbanions (S. Gronert).

4. Radicals (M. Newcomb).

5. Non-Kekul Molecules as Reactive Intermediates (J.A.Berson).

6. Organic Radical Ions (H.D. Roth).

7. Singlet Carbenes (M. Jones Jr. and R.A. Moss).

8. Stable Singlet Carbenes (G. Bertrand).

9. Triplet Carbenes (H. Tomioka).

10. Atomic Carbon (P.B. Shevlin).

11. Nitrenes (M.S. Platz).

12. Synthetic Carbene and Nitrene Chemistry (M.P. Doyle).

13. Nitrenium Ions (D.E. Falvey).

14. Silylenes (W. Ando and N. Tokitoh).

15. Strained Hydrocarbons: Structures, Stability, and Reactivity(K.B. Wiberg).

16. Arynes (M. Winkler, et al.).

PART 2: METHODS AND TEMPORAL REGIMES.

17. Matrix Isolation (T. Bally).

18. Nanosecond Laser Flash Photolysis: A Tool for Physica lOrganic Chemistry (J.C. Scaiano).

19. The Picosecond Realm (E. Hilinski).

20. Reactions on the Femtosecond Time Scale (J.E. Baldwin).

21. Potential Energy Surfaces and Reaction Dynamics (B.K.Carpenter).

22. The Partnership Between Electronic Structure Calculationsand Experiments in the Study of Reactive Intermediates (W.T.Borden).

Index.

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