The Science and Technology of Silicones and Silicone-Modified Materials / Edition 1

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Overview


The world-wide sales of polysiloxanes or silicones at the beginning of this new millennium is approximately $10 billion per year. Commercial products range from those entirely composed of silicone to products where the silicone is a low level but key component. This symposium covered the recent academic and technological developments behind silicones and silicone-modified materials and the sessions were well attended of wide interest to both the academic and industrial communities. The papers from our two highly successful symposia in this important area were published in the books Silicones and Silicone-Modified Materials, (Eds. S. J. Clarson, J. J. Fitzgerald, M. J. Owen and S. D. Smith), ACS Symposium Series Vol. 729 / Oxford University Press, 2000, ISBN 0-8412-3613-5 and Synthesis and Properties of Silicones and Silicone-Modified Materials, (Eds. S. J. Clarson, J. J. Fitzgerald, M. J. Owen, S. D. Smith and M. E. Van Dyke), ACS Symposium Series Vol 838 / Oxford University Press, 2003, ISBN 0-8412-3804-9
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Product Details

  • ISBN-13: 9780841239432
  • Publisher: American Chemical Society
  • Publication date: 8/2/2007
  • Series: ACS Symposium Series , #964
  • Edition number: 1
  • Pages: 400
  • Product dimensions: 9.10 (w) x 6.00 (h) x 1.00 (d)

Table of Contents

Preface     xiii
Introduction
Say Yes to Silicones! [Si to Si!]   Michael J. Owen     2
Synthesis
Tertiary Silyloxonium Ions in the Ring-Opening Polymerization (ROP) of Cyclosiloxanes: Cationic ROP of Octamethyltetrasila-1,4-dioxane   Marek Cypryk   Julian Chojnowski   Jan Kurjata     10
Synthesis of Novel Silicon-Containing Monomers for Photoinitiated Cationic Polymerization   James V. Crivello   Myoungsouk Jang     27
Fluorinated Copoly(carbosiloxane)s: Synthesis, Copolymerization, and Cross-Linked Networks   Melissa A. Grunlan   Nam S. Lee   John A. Finlay   James A. Callow   Maureen E. Callow   William P. Weber     37
Sulfidosilanes: Complex Molecule Systems via Phase Transfer Catalysis   Michael W. Backer   John M. Gohndrone   Simon D. Cook   Simeon J. Bones   Raquel Vaquer-Perez     49
Catalysts for Silane and Silanol Activation   J. B. Baruah     69
Copolymers
Copolymers Based on Dimethylsiloxane and Diphenylsiloxane Units   Thomas M. Gadda   William P. Weber     82
Silicone-Urea Copolymers Modified with Polyethers   Iskender Yilgor   Emel Yilgor     100
Application of Poly(styrene-b-methylphenylsiloxane) Diblock Copolymers for the Steric Stabilization of Organic Polymerizations in Carbon Dioxide   Abhijit V. Jadhav   Siddharth V. Patwardhan   Hyeon Woo Ahn   Craig E. Selby   James O. Stuart   Xiao Kang Zhang   Chung Mien Kuo   Ephraim A. Sheerin   Richard A. Vaia   Steven D. Smith   Stephen J. Clarson     116
Networks
Large-Scale Structures in Some End-Linked Polysiloxane Networks: A Critical Review   Brent D. Viers   James E. Mark     136
A Comparison of Poly(methylphenylsiloxane) and Poly(dimethylsiloxane) Membranes for the Removal of Low Molecular Weight Organic Compounds from Water by Pervaporation   Xiao Kang Zhang   Yadagiri Poojari   Stephen J. Clarson     165
Synthesis of Carbosilane Dendrimer-Based Networks   Aleksandra V. Bystrova   Elene A. Tatarinova   Aziz M. Muzafarov     176
The Gel Point and Network Formation Including Poly(dimethylsiloxane) Polymerizations: Theory and Experiment   J. I. Cail   R. F. T. Stepto     190
Use of Solubility Parameters for Predicting the Separation Characteristics of Poly(dimethylsiloxane) and Siloxane-Containing Membranes   Alexander R. Anim-Mensah   James E. Mark   William B. Krantz     203
Surfaces and Interfaces
Manipulating Siloxane Surfaces: Obtaining the Desired Surface Function via Engineering Design   Julie A. Crowe   Kirill Efimenko   Jan Genzer     222
Proteins at Silicone Interfaces   Paul M. Zelisko   Amro M. Ragheb   Michael Hrynyk   Michael A. Brook     256
Silsesquioxanes
Brewster Angle Microscopy Studies of Aggregate Formation in Blends of Amphiphilic Trisilanolisobutyl-POSS and Nitrile Substituted Poly(dimethylsiloxane) at the Air-Water Interface   Hyong-Jun Kim   Jennifer Hoyt Lalli   Judy S. Riffle   Brent D. Viers   Alan R. Esker     268
Hydrophobic Silsesquioxane Nanoparticles and Nanocomposite Surfaces: An Overview of the Synthesis and Properties of Fluorinated Polyhedral Oligomeric Silsequioxanes (POSS) and Fluorinated POSS Nanocomposites   Joseph M. Mabry   Ashwani Vij   Brent D. Viers   Wade W. Grabow   Darrell Marchant   Scott T. Iacono   Patrick N. Ruth   Isha Vij     290
Formation and Functionalization of Aryl-Substituted Silsesquioxanes   Yusuke Kawakami   Dong Woo Lee   Chitsakon Pakjamsai   Makoto Seino   Akiko Takano   Akio Miyasato   Ichiro Imae     301
Transparent Polymer-Polyhedral Oligomeric Silsesquioxane Composites    Subramanian Iyer   Amjad Abu-Ali   Andrew Detwiler   David A. Schiraldi     313
Silica and Related Systems
The Interaction of 'Silicon' with Proteins: Part 2. The Role of Bioinspired Peptide and Recombinant Proteins in Silica Polymerization   Siddharth V. Patwardhan   Kiyotaka Shiba   Heinz C. Schroder   Werner E. G. Muller   Stephen J. Clarson   Carole C. Perry     328
Synthesis of Styryl- and Methacryloxypropyl-Modified Silica Particles Using the Hydrolytic Sol-Gel Method and the Miniemulsion Polymerization Approach   Anna Arkhireeva   John N. Hay     348
Indexes
Author Index     371
Subject Index     373
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