Silicon Chemistry

Overview

Silicon and silicon compounds have contributed decisively to the technical progress. Technical applications range from mass commodities to highly sophisticated special materials, from ceramics to polymers, from medicine to microelectronics. To keep pace with scientific and technical developments Germany and Austria have established national priority programs, strongly linked to each other as well as to some Swiss groups.
At mid-term of the German program and the end of the first...

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Overview

Silicon and silicon compounds have contributed decisively to the technical progress. Technical applications range from mass commodities to highly sophisticated special materials, from ceramics to polymers, from medicine to microelectronics. To keep pace with scientific and technical developments Germany and Austria have established national priority programs, strongly linked to each other as well as to some Swiss groups.
At mid-term of the German program and the end of the first funding period of the Austrian program the results are summarized in this special edition of the journal Monatshefte für Chemie/Chemical Monthly, giving an excellent overview of the current chemical (and partly physical) acitivites in the joint Austrian/German/Swiss program.
The contributions cover topical and interdisciplinary developments in the following areas:
• new phenomena in compounds with Si-Si bonds: transitions between molecular compounds and solids, cyclosilanes, polysilanes, silicides, amorphous hydrogenated silicon,
• novel silicon-oxygen systems: functionalized sol-gel compounds, spherosiloxanes, siloxene,
• compounds with low- and high-coordinated silicon,
• new spectroscopic and analytical techniques for the characterization of molecular and polymeric silicon compounds.

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Product Details

  • ISBN-13: 9783211832783
  • Publisher: Springer Vienna
  • Publication date: 3/28/1999
  • Edition description: 1999
  • Edition number: 1
  • Pages: 242

Table of Contents

Editorial 1
Carbosilane Dendrimers - Synthesis, Functionalization, Application 3
Synthesestrategien zur Darstellung von unterschiedlich funktionalisierten Cyclosiloxanen sowie Additions- und Substitutionsreaktionen eines Al[subscript 4](OH)[subscript 4]-Achtringes in einem molekularen Oligoalumosiloxan 15
Structure Determining Effect of Alcohols and Water on the Shape of the Hydrogen Bonded Network in Adducts with (9-Methyl-fluoren-9-yl)-silanetriol 33
Silsesquioxane Chemistry II. Tin(IV) and Hafnium(IV) Compounds of Silsesquioxanes 45
Photolumineszenzeigenschaften von substituierten Silsesquioxanen der Zusammensetzung R[subscript n](SiO[subscript 1.5])[subscript n] 55
Gezielte Synthese siloxenahnlicher Polymere 69
Preparation and Characterization of Epitaxial CaSi[subscript 2] and Siloxene Layers on Silicon 79
Synthesis of Alkoxysilyl Substituted Cyclophosphazenes and their Properties in the Sol-Gel Process 89
A Zwitterionic [lambda][superscript 5]Si-Silicate with an Almost Ideal Square-Pyramidal Si Coordination Polyhedron: Synthesis and Crystal Structure Analysis 99
Preparation and Structure of 1-(Trifluoro-methyl)silatrane 109
Hexacoordinate Silicon-Azomethine Complexes: Synthesis, Characterization, and Properties 117
Hexa(amino)disilanes with Saturated Cyclic Amino Ligands 133
Synthesis and Structure of P[subscript 7][Si(SiMe[subscript 3])[subscript 3]][subscript 3] (Tri(hypersilyl)heptaphosphanortricyclane) 139
Solid-State Molecular Dynamics of (Ph[subscript 3]Si)Si(SiMe[subscript 3])[subscript 3] Studied by Variable Temperature [superscript 13]C and [superscript 29]Si MAS NMR Spectroscopy 147
Reactions of a Cyclotrisilane with Chalcogen Transfer Reagents 157
Zur Charakterisierung von Si-Polymeren durch flussigchromatographische Verfahren in Kopplung mit MALDI-TOF-MS 163
Phase Behaviour of Poly(di-n-decylsilane) 175
Synthese, Funktionalisierung und Vernetzung von Poly(silylenphenylenen) 181
Sr[subscript 12]Mg[subscript 17.8]Li[subscript 2.2]Si[subscript 20], die erste Zintl-Phase mit einer Si[subscript 3]-Kette 197
Oligosilylanions and their Reactions with Zirconocene and Hafnocene Dichlorides 203
Transition Metal Silyl Complexes LVIII. Silyl Group Exchange between (R[subscript 3]P)[subscript 2]Pt(SiR[subscript 3])[subscript 2] und HSiR[subscript 3] 207
Group IV Metallocene Bis(trimethylsilyl)acetylene Complexes as Catalysts in the Dehydrocoupling Polymerization of 1,2-Disubstituted Hydrodisilanes 215
Deposition of Amorphous Hydrogenated Silicon ([alpha]-Si:H): in situ Gas Analysis by Time-of-Flight Mass Spectrometry 221
Reaktion von atomarem Silicium mit Methanol: Matrixspektroskopische Identifizierung von Methoxysilylen 227
Zum Spreitverhalten von Mischungen definierter Trisiloxantenside auf niederenergetischen Oberflachen 237
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