Structured Catalysts and Reactors

Overview

Structured Catalysts and Reactors, Second Edition gives detailed information on all aspects of structured catalysts and reactors, including: materials, mass transfer, selectivity, activity, and stability; catalyst preparation, design, and characterization; process development; modeling and optimization; reactor design; and operation costs and considerations.

The book examines how monolithic catalysts are used to clean exhaust gas from gasoline engines, treat industrial ...

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Overview

Structured Catalysts and Reactors, Second Edition gives detailed information on all aspects of structured catalysts and reactors, including: materials, mass transfer, selectivity, activity, and stability; catalyst preparation, design, and characterization; process development; modeling and optimization; reactor design; and operation costs and considerations.

The book examines how monolithic catalysts are used to clean exhaust gas from gasoline engines, treat industrial off-gases, burn fuels in commercial settings, and synthesize chemicals in two- and three-phase processes. It discusses ceramic and metallic monoliths before directing its focus to arranged catalysts and structured packings. The book explores catalytically active membranes and filters, featuring metallic membranes, permeation mechanisms, preparation and modeling, commercial membranes, and the latest applications, such as zeolitic membranes. Several chapters present techniques for incorporating catalytic species into the structured catalyst support and controlling nanoporosity.

This book conveys the scientific as well as economic advantages of using these unconventional catalytic techniques. With over 1500 references, tables, drawings, and photographs, as well as in-depth discussions and a new approach to catalytic processes, Structured Catalysts and Reactors, Second Edition is an essential reference for anyone working with or studying catalysis.

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Editorial Reviews

Booknews
Examines a type of catalyst that shows promise of eliminating the chemical and thermal distortions often encountered when using fixed- bed reactors in the chemical industry. After an overview, 22 independent treatments cover reactors using monolithic or honeycomb catalysts in which there is no convective mass transfer over a cross- section of the reactor; those in which there is such transfer; monolithic reactors with permeable walls, called membrane reactors; and preparing and characterizing catalysts. The specific topics include the computer-aided characterization and design of a catalyst pore structure, ceramic catalyst supports and filters for diesel exhaust aftertreatment, parallel-passage and lateral-flow reactors, modeling monolith reactors in three-phase processes, the unconventional utilization of monolithic catalysts for gas-phase reactions, and metal and coated-metal catalysts. Annotation c. by Book News, Inc., Portland, Or.
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Product Details

  • ISBN-13: 9780824799212
  • Publisher: CRC Press
  • Publication date: 10/24/1997
  • Series: Chemical Industries Series
  • Pages: 688
  • Product dimensions: 6.90 (w) x 10.10 (h) x 1.50 (d)

Table of Contents

Ch. 1 The present and the future of structured catalysts : an overview 1
Pt. I Reactors with structured catalysts where no convective mass transfer over a cross section of the reactor occurs (monolithic catalysts = honeycomb catalysts) 19
Ch. 2 Ceramic catalyst supports for gasoline fuel 21
Ch. 3 Metal and coated metal catalysts 71
Ch. 4 Autocatalysts : past, present, and future 109
Ch. 5 Treatment of volatile organic carbon (VOC) emissions from stationary sources : catalytic oxidation of the gaseous phase 147
Ch. 6 Monolithic catalysts for NO[subscript x] removal from stationary sources 171
Ch. 7 Catalytic fuel combustion in honeycomb monolith reactors 215
Ch. 8 Monolithic catalysts for gas-phase syntheses of chemicals 243
Ch. 9 Modeling of automotive exhaust gas converters 311
Ch. 10 Monolithic catalysts for three-phase processes 355
Ch. 11 Two-phase segmented flow in capillaries and monolith reactors 393
Ch. 12 Modeling and design of monolith reactors for three-phase processes 435
Ch. 13 Film flow monolith reactors 479
Pt. II Reactors with structured catalysts where convective mass transfer over the cross section of the reactor occurs 507
Ch. 14 Parallel-passage and lateral-flow reactors 509
Ch. 15 Structured packings for reactive distillation 539
Pt. III Monolithic reactors with permeable walls (membrane reactors) 551
Ch. 16 Catalytic filters for flue gas cleaning 553
Ch. 17 Reactors with metal and metal-containing membranes 579
Ch. 18 Inorganic membrane reactors 615
Ch. 19 Ceramic catalysts, supports, and filters for diesel exhaust after-treatment 663
Ch. 20 Zeolite membranes : modeling and application 701
Pt. IV Catalyst preparation and characterization 749
Ch. 21 Transformation of a structured carrier into a structured catalyst 751
Ch. 22 Structuring catalyst nanoporosity 779
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