Supramolecular Engineering of Synthetic Metallic Materials: Conductors and Magnets

Overview

The creation of molecular materials that have desired electrical conductance and magnetic properties demands the precise arrangement of molecules in the solid state. Such controlled arrangement has been achieved very elegantly by supramolecular chemists, especially those practising crystal engineering.
This book, which presents articles by foremost experts in crystal engineering, molecular conductors and magnetic magnetism, reveals the results of an interdisciplinary union that ...

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2012 Paperback NEAR FINE Paperback, This listing is a new book, a title currently in-print which we order directly and immediately from the publisher. *****PLEASE NOTE: This ... item is shipping from an authorized seller in Europe. In the event that a return is necessary, you will be able to return your item within the US. To learn more about our European sellers and policies see the BookQuest FAQ section***** Read more Show Less

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Overview

The creation of molecular materials that have desired electrical conductance and magnetic properties demands the precise arrangement of molecules in the solid state. Such controlled arrangement has been achieved very elegantly by supramolecular chemists, especially those practising crystal engineering.
This book, which presents articles by foremost experts in crystal engineering, molecular conductors and magnetic magnetism, reveals the results of an interdisciplinary union that may well have a profound influence on the future of materials science. Theoretical studies reveal potential areas of interest for those investigating molecular conductors and magnets, as well as materials that exhibit both properties.
A unique survey of the state of the art appealing to all those doing research in supramolecular chemistry and materials science.

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Editorial Reviews

Booknews
The 29 papers from the January 1998 workshop discuss recent results and future trends in the areas of crystal engineering, molecular conductors, and molecular magnets. The three introductory chapters give the basic concepts and fundamentals of crystal engineering for the design and prediction of molecular solids. The next three chapters contain experimental results concerning the synthesis and characterization of molecular solids. Another eight contributions deal with the design and study of molecular materials showing magnetic properties. The following eight papers address materials combining magnetic with electrical properties. The volume concludes with seven contributions that describe results on the synthesis of new molecules forming molecular conductors. Annotation c. by Book News, Inc., Portland, Or.
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Product Details

  • ISBN-13: 9789401062220
  • Publisher: Springer Netherlands
  • Publication date: 12/31/2013
  • Series: Nato Science Series C: (closed)
  • Edition description: Softcover reprint of the original 1st ed. 1999
  • Pages: 493

Table of Contents

Preface
List of contributors
Some Current Challenges in Crystal Engineering 1
Structural and Crystallographic Aspects of Supramolecular Engineering Structure-Property Relations, Polymorphism and Crystal Growth 23
The Computer Prediction of the Assembling of Organic Molecules into Crystals: A Perspective 41
Molecular Networks: An Approach to Coordination Polymers 53
The Prediction and Production of Polar Molecular Materials: From Markov's Theory to Crystal Growth 67
NMR Spectroscopy and the Development of Structural Models for Crystalline Supramolecular Solids - Applications to p-tert-butyicalix[4]arenes 83
Crystal Engineering of Purely Organic Molecular Magnets: What can ab initio Computations Tell us? 105
Hysteresis and Memory Effect in Supramolecular Chemistry 127
Tunable Nitroxide Free Radical Ligands: From Zero- to Two-Dimensional Metal-Radical Networks 145
Examples of Supramolecular Coordination Compounds and their Supramolecular Functions 175
Manganoporphyrin TCNE Electron Transfer Complexes - Structure-Function Correlations 197
Dithiadiazolyl Radicals as Molecular Bricks for High T[subscript c] Organic Magnets 217
Host-Guest Interactions for Tuning the Magnetic Coupling in Metal Ion Clusters 231
Exotic Crystal Structures and Magnetic Properties of NitronyInitroxide Cation Radical Salts. Collapse of Spin-Gap Ground State in Distorted Antiferromagnetic Kagome Lattices 241
Conductivity, Chirality and Conductivity in Layer Molecular Magnets 253
Molecular Conductors and Magnets: Structure-Property Relationships 271
Hybrid Materials Formed by Two Molecular Networks. Magnetic Conductors, Magnetic Multilayers and Magnetic Films 291
Interplay of Conductivity and Magnetism in BETS-Derived Compounds (BETS = bis(ethylenedithio)tetraselenafulvalene) 313
The Flexibility of Molecular Components as a Tool in the Construction of Conducting and Magnetic Systems 329
Hydrogen Bonding and Transport Properties of Molecular Conductors 337
Insight into the Behavior of M(TCNQ)[subscript n] (n = 1,2) Crystalline Solids and Films: X-Ray, Magnetic and Conducting Properties 353
Tetrathiafulvalene (TTF) Derivatives as Versatile Building Blocks: From Metals to Spin Ladders 377
Novel Hyper Electron-Accepting Molecules for Development of Organic Materials 393
Low-Dimensional Organic Superconductors [kappa]-(BEDT-TTF)[subscript 2]Cu[N(CN)[subscript 2]]X, where X = Br[subscript 0.5]Cl[subscript 0.5], Br[subscript 0.7]Cl[subscript 0.3] and Br[subscript 0.9]I[subscript 0.1] 409
Tetrathiafulvalenes: Building Blocks in Macrocyclic and Supramolecular Chemistry 419
A New Range of Functionalised Tetrathiafulvalenes and their Cation Radical Salts: Synthetic and Solid State Studies 437
New Tetrathiafulvalenes for Advanced Materials 451
Metal Phosphonate Langmuir-Blodgett Films: Magnetic Monolayers and Organic/Inorganic Dual Network Assemblies 465
Supramolecular Engineering of Conducting Thin Films by Covalently Hinging Electroactive Molecular Surfactants 477
Subject Index 485
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