The Organometallic Chemistry of the Transition Metals / Edition 1

The Organometallic Chemistry of the Transition Metals / Edition 1

by Robert H. Crabtree
     
 

ISBN-10: 0471853062

ISBN-13: 9780471853060

Pub. Date: 02/12/1988

Publisher: Wiley

Presents organometallic chemistry within a logical framework of fundamental ideas. Deals with practical applications of the subject, processes of industrial significance, and organic synthesis. The biological aspects of the subject, which are just beginning to emerge, are also covered. Discusses methods of characterization and of bio-organometallic chemistry,

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Overview

Presents organometallic chemistry within a logical framework of fundamental ideas. Deals with practical applications of the subject, processes of industrial significance, and organic synthesis. The biological aspects of the subject, which are just beginning to emerge, are also covered. Discusses methods of characterization and of bio-organometallic chemistry, neither of which is treated in the standard texts available. There is also coverage of high valent organometallic species and of applications to organic synthesis.

Product Details

ISBN-13:
9780471853060
Publisher:
Wiley
Publication date:
02/12/1988
Pages:
422
Product dimensions:
6.30(w) x 9.25(h) x 1.18(d)

Table of Contents

1Introduction1
2General properties of organometallic complexes29
3Metal alkyls, aryls, and hydrides and related [sigma]-bonded ligands53
4Carbonyls, phosphine complexes, and ligand substitution reactions87
5Complexes of [pi]-bound ligands125
6Oxidative addition and reductive elimination159
7Insertion and elimination183
8Nucleophilic and electrophilic addition and abstraction207
9Homogeneous catalysis235
10Physical methods in organometallic chemistry275
11Metal-ligand multiple bonds309
12Applications of organometallic chemistry343
13Clusters and the metal-metal bond379
14Applications to organic synthesis417
15Paramagnetic, high-oxidation-state, and high-coordination-number complexes463
16Bioorganometallic chemistry491

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