Ylides and Imines of Phosphorus / Edition 1

Ylides and Imines of Phosphorus / Edition 1

by A. William Johnson, K. Alexander Starzewski, William C. Kaska
     
 

ISBN-10: 0471522171

ISBN-13: 9780471522171

Pub. Date: 08/05/1993

Publisher: Wiley

Provides overview of ylide and imine chemistry of phosphorous. Contains over 3,150 references. Focuses on their application, particularly in organic synthesis. Presents up-to-date understanding of structure, bonding and behavior of each type of ylide. Covers ylide preparations, handling and decomposition. Features theoretical descriptions of the bonding in ylides

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Overview

Provides overview of ylide and imine chemistry of phosphorous. Contains over 3,150 references. Focuses on their application, particularly in organic synthesis. Presents up-to-date understanding of structure, bonding and behavior of each type of ylide. Covers ylide preparations, handling and decomposition. Features theoretical descriptions of the bonding in ylides and the reactions of phosphorous ylides with transition metal compounds.

Product Details

ISBN-13:
9780471522171
Publisher:
Wiley
Publication date:
08/05/1993
Pages:
624
Product dimensions:
6.50(w) x 9.45(h) x 1.38(d)

Table of Contents

Theoretical Description of the Bonding in Ylides.

Introduction to Phosphonium Ylides.

Preparation of Phosphonium Ylides.

Reactions of Phosphonium Ylides 1: Cleavages and Decompositions.

Reactions of Phosphonium Ylides 2: With Electrophilic Reagents.

Reactions of Phosphonium Ylides 3: With Multiple-Bonded Compounds and Three-Membered Rings.

The Wittig Reaction 1: Scope and Applications.

The Wittig Reaction 2: Mechanism and Stereochemistry.

Phosphonate Carbanions (Phosphono Ylides).

Phosphinoxy Carbanions (Phosphino Ylides).

Other Phosphorus Ylides/Carbanions.

Iminophosphoranes and Related Compounds.

Transition Metal Complexes with Ylides.

Index.

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