Table of Contents
Preface ix
Introduction xi
Contributors xiii
SECTION I O VERVIEW OF POLYMERIZAT ION REACTIONS AND KINETICS_1
1 Free Radical and Condensation Polymerizations 3
Matthew Kade and Matthew Tirrell
2 Overview of Controlled/Living Polymerization Methods of Vinyl Monomers 29
Robert T. Mathers, Andrew J. D. Magenau, Kristin Schröder, and Krzysztof Matyjaszewski
3 Stimuli-Responsive Polymers via Controlled Radical Polymerization 45
Joel D. Flores, Brooks A. Abel, DeeDee Smith, and Charles L. McCormick
4 Reactions in Heterogeneous Media: Emulsion, Miniemulsion, Microemulsion, Suspension, and Dispersion Polymerization 59
Radmila Tomovska, José C. de la Cal, and José M. Asua
SECTION 2 Polym erization Characterization and Monitoring Methods 79
5 Polymer Characteristics 81
Wayne F. Reed
6 Infrared (MIR, NIR), Raman, and Other Spectroscopic Methods 107
Alexandre F. Santos, Fabricio M. Silva, Marcelo K. Lenzi, and José C. Pinto
7 Calorimetry, Conductivity, Densimetry, and Rheological Measurements 135
Jose R. Leiza and Timothy McKenna
8 Light Scattering 151
Guy C. Berry
9 G PC/SEC as a Key Tool for Assessment of Polymer Quality and Determination of Macromolecular Properties 171
Daniela Held and Peter Kilz
10 Mass Spectroscopy: ESR and NMR Applications to Polymer Characterization and Polymerization Monitoring 201
Zifu Zhu and Alina M. Alb
SECTION 3 A utomatic Continuous Online Monitoring of Polymerization Reactions (ACOMP) 229
11 Background and Principles of Automatic Continuous Online Monitoring of Polymerization Reactions (ACOMP) 231
Wayne F. Reed
12 Applications of ACOMP (I) 247
Alina M. Alb
13 Applications of ACOMP (II) 271
Wayne F. Reed
14 Cognate Techniques to ACOMP 295
Michael F. Drenski, Alina M. Alb, and Wayne F. Reed
15 Outlook for Industrial ACOMP 313
Michael F. Drenski and Alex W. Reed
SECTION 4 Reactor Control and Design: Batch, Semi-batch, and Continuous Reactors 325
16 Mathematical Modeling of Polymerization Reactors 327
F. Joseph Schork
17 Design and Operation of Polymerization Reactors 345
F. Joseph Schork
18 Optimization of the Particle Size in Emulsion Polymerization 363
Joseph Zeaiter and José A. Romagnoli
SECTION 5 Industrial Applications 381
19 Water-Soluble Free Radical Addition Polymerizations 383
Wesley L. Whipple and Hua Zheng
20 Protein Aggregation in Pharmaceutical Biotechnology 395
Mark L. Brader
21 Rubbers and Elastomers 409
Jorge Soto
22 Polymers from Natural Products 427
Dimitrios Samios, Aline Nicolau, and Miriam B. Roza
Index 451