ISBN-10:
0841274142
ISBN-13:
9780841274143
Pub. Date:
07/09/2007
Publisher:
American Chemical Society
Recent Developments in Carbocation and Onium Ion Chemistry

Recent Developments in Carbocation and Onium Ion Chemistry

by Kenneth Laali

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Product Details

ISBN-13: 9780841274143
Publisher: American Chemical Society
Publication date: 07/09/2007
Series: ACS Symposium Series , #965
Pages: 544
Product dimensions: 9.10(w) x 6.20(h) x 1.20(d)

About the Author

Ken Laali received his PhD in organofluorine chemistry in 1977 from University of Manchester (Robert Haszeldine and Brian Booth); following postdoctoral stints in Europe (1977-1982) at King's College London (V. Gold), Strasbourg (J. Sommer), Amsterdam (H. Cerforntain), and ETH-Zurich (H. Zollinger), he moved to Univ. Southern California in 1982 to work with George Olah. In 1985 he accepted a faculty position at Kent State University, becoming full professor in 1996.

Table of Contents

Foreword
Preface
Chapter 1. Experimental and computational NMR spectroscopic investigation of silyl-substituted carbocations
Chapter 2. Super-Stabilization of -Conjugated Cations by Annelation to Bicyclic Frameworks
Chapter 3. Unusually Stable Vinyl Cations
Chapter 4. Vinyl Iodonium Salts as Precursors to Vinyl Cations
Chapter 5. Generation of Alkylideneallyl Cations from Alkylidenecyclopropanone Acetals Selectivity of Reaction with Nucleophiles
Chapter 6. Conformational Studies of Cyclobutylmethyl Cations
Chapter 7. Persistent Organic Cationic Complexes: Structure and Reactivity
Chapter 8. Activation of Electrophilic Sites by Adjacent Cationic Groups
Chapter 9. Stabilized Carbocations as Redox Active Chromophores Preparation of Electrochromic Materials Using Stabilized Carbocations
Chapter 10. Cation Pool Method and Cation Flow Method
Chapter 11. Fluorenylidene and Indenylidene Dications: Insights about Antiaromaticity
Chapter 12. Generation, Stability, and Reactions of Alkylated Fullerene Cations
Chapter 13. Carbocations on Surfaces
Formation of Bicyclobutonium Cation via Ionization of Cyclopropylcarbinyl Chloride Over NaY Zeolite
Chapter 14. MO Calculations involving µ-hydrido cation intermediates relevant to the heptane to toluene dehydrocyclization reaction
Chapter 15. Theoretical Studies on Structure and Dynamics of Carbonium Ions
Chapter 16. Quantum Chemical Studies of Carbocations from Oxidized Metabolites of Aza-Polycyclic Aromatic Hydrocarbons (Aza-PAHs)
Chapter 17. How Does Carbocation Stability Control the Beckmann Rearrangement Reaction?
Chapter 18. Solvent Effects on the Chemistry of Bromonium and -Bromo-carbenium Ions as Reactive Intermediates
Chapter 19. Syntheses of the CFY2+ (Y = Cl, Br) and CX3+ (X = Cl, Br, OTeF5) Cations Employing the Noble-Gas Oxidant, XeOTeF5+Sb(OTeF5)6?
Chapter 20. Organoxenonium Salts
Synthesis by "Xenodeborylation", Reactivities, and NMR Spectroscopic Properties
Chapter 21. Halogen transfer reactions from bis-amino halonium ions to acceptor olefins: mechanism and strategies for chiral halogenation
Chapter 22. Synthesis of Phosphonium Salts by Metal-Catalyzed Addition Reaction

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