ISBN-10:
0792332520
ISBN-13:
9780792332527
Pub. Date:
11/30/1994
Publisher:
Springer Netherlands
Collision- and Interaction-Induced Spectroscopy / Edition 1

Collision- and Interaction-Induced Spectroscopy / Edition 1

by G.C. Tabisz, Murray N. Neuman

Hardcover

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Overview

Collision-or interaction-induced spectroscopy refers to radiative transitions, which are forbidden in free atoms or molecules, but which occur in clusters of interacting atoms or molecules. The most common phenomena are induced absorption, in the infrared region, and induced light scattering, which involves inelastic scattering of visible laser light. The particle interactions giving rise to the necessary induced dipole moments and polarizabilities are modelled at long range by multipole expansions; at short range, electron overlap and exchange mechanisms come into play. Information on atomic and molecular interactions and dynamics in dense media on a picosecond timescale may be drawn from the spectra. Collision-induced absorption in the infrared was discovered at the University of Toronto in 1949 by Crawford, Welsh and Locke who studied liquid O and N. Through the 1950s and 1960s, 2 2 experimental elucidation of the phenomenon, particularly in gases, continued and theoretical underpinnings were established. In the late 1960s, the related phenomenon of collision-induced light scattering was first observed in compressed inert gases. In 1978, an 'Enrico Fermi' Summer School was held at Varenna, Italy, under the directorship of J. Van Kranendonk. The lectures, there, reviewed activity from the previous two decades, during which the approach to the subject had not changed greatly. In 1983, a highly successful NATO Advanced Research Workshop was held at Bonas, France, under the directorship of G. Birnbaum. An important outcome of that meeting was the demonstration of the maturity and sophistication of current experimental and theoretical techniques.

Product Details

ISBN-13: 9780792332527
Publisher: Springer Netherlands
Publication date: 11/30/1994
Series: Nato Science Series C: , #452
Edition description: 1995
Pages: 588
Product dimensions: 6.10(w) x 9.25(h) x 0.36(d)

Table of Contents

Preface. Section A: Interactions. Section B: Fluids at Liquid and Near-Liquid Densities. Section C: Complex Liquids. Section D: Solids and Inclusion Complexes. Section E: Electronic Spectra. Section G: Dimers. Section H: Astrophysics. Section I: Assessment. Author Index. Chemical Index. Subject Index.

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