Endohedral Fullerenes: From Fundamentals To Applications
Endohedral fullerenes represent a novel family of carbon nanostructures, which are characterized by a robust fullerene cage with atoms, ions, or clusters trapped in its interior. Since the first separation of the endohedral metallofullerene La@C82 in 1991, a large variety of endohedral structures have been isolated and their endohedral nature has been proved by experimental studies. Within the past two decades, the world of endohedral fullerenes was significantly enlarged by the clusterfullerenes and the new carbon cages including non-IPR (IPR=isolated pentagon rule) structures. Resulting from the charge transfer from the encaged species to the fullerene cage, endohedral fullerenes hold a lot of fascinating properties inaccessible by the empty fullerenes, and consequently promise potential applications in biomedicine, molecular electronics and photonics etc.The book provides a comprehensive overview of endohedral fullerenes focused on the new advances in the past decade, including its fundamentals (structures), synthesis, isolation, characterization, properties, functionalization as well as the applications, thus representing the most updated and broad review of this exciting field.
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Endohedral Fullerenes: From Fundamentals To Applications
Endohedral fullerenes represent a novel family of carbon nanostructures, which are characterized by a robust fullerene cage with atoms, ions, or clusters trapped in its interior. Since the first separation of the endohedral metallofullerene La@C82 in 1991, a large variety of endohedral structures have been isolated and their endohedral nature has been proved by experimental studies. Within the past two decades, the world of endohedral fullerenes was significantly enlarged by the clusterfullerenes and the new carbon cages including non-IPR (IPR=isolated pentagon rule) structures. Resulting from the charge transfer from the encaged species to the fullerene cage, endohedral fullerenes hold a lot of fascinating properties inaccessible by the empty fullerenes, and consequently promise potential applications in biomedicine, molecular electronics and photonics etc.The book provides a comprehensive overview of endohedral fullerenes focused on the new advances in the past decade, including its fundamentals (structures), synthesis, isolation, characterization, properties, functionalization as well as the applications, thus representing the most updated and broad review of this exciting field.
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Endohedral Fullerenes: From Fundamentals To Applications

Endohedral Fullerenes: From Fundamentals To Applications

Endohedral Fullerenes: From Fundamentals To Applications

Endohedral Fullerenes: From Fundamentals To Applications

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Overview

Endohedral fullerenes represent a novel family of carbon nanostructures, which are characterized by a robust fullerene cage with atoms, ions, or clusters trapped in its interior. Since the first separation of the endohedral metallofullerene La@C82 in 1991, a large variety of endohedral structures have been isolated and their endohedral nature has been proved by experimental studies. Within the past two decades, the world of endohedral fullerenes was significantly enlarged by the clusterfullerenes and the new carbon cages including non-IPR (IPR=isolated pentagon rule) structures. Resulting from the charge transfer from the encaged species to the fullerene cage, endohedral fullerenes hold a lot of fascinating properties inaccessible by the empty fullerenes, and consequently promise potential applications in biomedicine, molecular electronics and photonics etc.The book provides a comprehensive overview of endohedral fullerenes focused on the new advances in the past decade, including its fundamentals (structures), synthesis, isolation, characterization, properties, functionalization as well as the applications, thus representing the most updated and broad review of this exciting field.

Product Details

ISBN-13: 9789814489836
Publisher: World Scientific Publishing Company, Incorporated
Publication date: 05/20/2014
Pages: 448
Product dimensions: 6.00(w) x 9.10(h) x 1.20(d)

Table of Contents

Dedication v

Foreword vii

Chapter 1 The Early Days of Metallofullerene Research Hisanori Shinohara 1

Chapter 2 Synthesis and Isolation of Endohedral Fullerenes - A General Review Fupin Liu Jian Guan Tao Wei Song Wang Shangfeng Yang 19

Chapter 3 Crystallographic Study of Endohedral Metallofullerenes Yun-Peng Xie Shasha Zhao Xing Lu 61

Chapter 4 Metal Nitride Clusterfullerenes - New Advances and Challenges Tao Wei Song Wang Fupin Liu Jian Guan Alexey A. Popov Lothar Dunsch Shangfeng Yang 99

Chapter 5 Metal Carbide Clusterfullerenes Taishan Wang Chunru Wang 137

Chapter 6 The Discovery of Non-IPR Fullerenes Wei Xu Chunying Shu Chunru Wang 153

Chapter 7 Metal Oxide Clusterfullerenes Steven Stevenson 179

Chapter 8 Nitrogen Atom-Based Endohedral Fullerenes and Potential Applications B. J. Fartington K. Porfyrakis 211

Chapter 9 Noble-Gas Fullerenes R. James Cross, Jr. 233

Chapter 10 Electrochemical Properties of Endohedral Metallofullerenes Luis Echegoyen Frederic Melin Manuel N. Chaur 253

Chapter 11 Chemical Functionalization of Endohedral Metallofullerenes Yutaka Maeda 281

Chapter 12 Computational Studies of Endohedral FuUerenes: Bonding, Isomerism, Internal Dynamics, Spectroscopy, and Chemical Reactivity Alexcy A. Popov 315

Chapter 13 Biomedical Applications of Trimetallic Nitride Endohedral Metallofullerenes Jianyuan Zhang Boris M. Kiselev Youqing Ye Harry C. Dorn 401

Chapter 14 Higher LUMO Level Endohedral Fullerene and Fullerene Bisadduct Acceptors for Polymer Solar Cells Yongfang Li 417

Index 433

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