Surface Modifications and Growth of Titanium Dioxide for Photo-Electrochemical Water Splitting

by John Alexander

Overview

This outstanding thesis provides a wide-ranging overview of the growth of titanium dioxide thin films and its use in photo-electrochemicals such as water splitting. The context for water splitting is introduced with the theory of semiconductor-liquid junctions, which are dealt with in detail. In particular plasmonic enhancement of TiO₂ by the addition of gold nanoparticles is considered in depth, including a thorough and critical review of the literature, which discusses the possible mechanisms that may be at work. Plasmonic enhancement is demonstrated with gold nanoparticles on Nb-doped TiO2. Finally, the use of temperature and pressure to control the phase and morphology of thin films grown by pulsed laser deposition is presented.

Product Details

ISBN-13:	9783319817088
Publisher:	Springer International Publishing
Publication date:	06/01/2018
Series:	Springer Theses
Edition description:	Softcover reprint of the original 1st ed. 2016
Pages:	336
Product dimensions:	6.10(w) x 9.25(h) x (d)

Table of Contents

Introduction.- Literature Review.- Principles of Photo-electrochemical Cells.- Experimental Methods.- Results: Plasmonic Phourrent with AuNP-TiO2.- Electrochemistry of TiO2 – Rutile (110).- TiO2 Thin Films on Fused Silica.- Epitaxial TiO2 Thin Films on Single Crystal Substrates.- Conclusions.