This thesis offers novel methods for catalyst and process design for the selective hydrogenation of acetylene and 1,3-butadiene. The author predicts the properties of supported Pd–Ni bimetallic catalysts using density functional theory (DFT) calculations and temperature-programmed desorption (TPD). The excellent correlation between model surfaces and supported catalysts demonstrates the feasibility of designing effective bimetallic catalysts for selective hydrogenation reactions. The author also proposes a method for designing non-precious metal catalysts to replace precious metals. She modifies the process of selective hydrogenation of acetylene by coupling the selective adsorption to the selective hydrogenation in the liquid phase, as a result of which the ethylene selectivity is greatly improved and heat transfer is greatly enhanced. Lastly, by analyzing the mechanism of liquid-phase hydrogenation, the author proposes a multi-stage slurry bed reactor for industrial applications.
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Catalytic and Process Study of the Selective Hydrogenation of Acetylene and 1,3-Butadiene
This thesis offers novel methods for catalyst and process design for the selective hydrogenation of acetylene and 1,3-butadiene. The author predicts the properties of supported Pd–Ni bimetallic catalysts using density functional theory (DFT) calculations and temperature-programmed desorption (TPD). The excellent correlation between model surfaces and supported catalysts demonstrates the feasibility of designing effective bimetallic catalysts for selective hydrogenation reactions. The author also proposes a method for designing non-precious metal catalysts to replace precious metals. She modifies the process of selective hydrogenation of acetylene by coupling the selective adsorption to the selective hydrogenation in the liquid phase, as a result of which the ethylene selectivity is greatly improved and heat transfer is greatly enhanced. Lastly, by analyzing the mechanism of liquid-phase hydrogenation, the author proposes a multi-stage slurry bed reactor for industrial applications.
109.99
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Catalytic and Process Study of the Selective Hydrogenation of Acetylene and 1,3-Butadiene
141
Catalytic and Process Study of the Selective Hydrogenation of Acetylene and 1,3-Butadiene
141Paperback(Softcover reprint of the original 1st ed. 2017)
$109.99
109.99
In Stock
Product Details
| ISBN-13: | 9789811092473 |
|---|---|
| Publisher: | Springer Nature Singapore |
| Publication date: | 07/11/2018 |
| Series: | Springer Theses |
| Edition description: | Softcover reprint of the original 1st ed. 2017 |
| Pages: | 141 |
| Product dimensions: | 6.10(w) x 9.25(h) x (d) |
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