Solubilization in Surfactant Aggregates / Edition 1

by Sherril D. Christian, John F. Scamehorn

Overview

This work covers topics ranging from fundamental studies of solubilization to practical technological applications of the phenomenon. It reviews the solubilization of organic materials into surfactant aggregates, including micelles, vesicles and admicelles. The book also details methods of measuring solubilization that utilize both classical and newer instrumental techniques. It is intended for physical, surface, colloid and surfactant chemists; chemical, environmental and civil engineers; and upper-level undergraduate and graduate students in these disciplines.

Product Details

ISBN-13:	9780367401795
Publisher:	Taylor & Francis
Publication date:	09/05/2019
Series:	Surfactant Science
Edition description:	Reprint
Pages:	564
Product dimensions:	6.00(w) x 9.00(h) x (d)

About the Author

Sherril D. Christian, John F. Scamehorn

Table of Contents

Preface v

Contributors xi

I Overview

1 Overview and History of the Study of Solubilization Connie S. Dunaway Sherril D. Christian John F. Scamehorn 3

II Solubilization in Micelles

2 Solubilization of Gases Allen D. King, Jr. 35

3 Thermodynamics of Solubilization of Polar Additives in Micellar Solutions Rosario De Lisi Stefania Milioto 59

4 Solubilization of Uncharged Molecules in Ionic Micellar Solutions: Toward an Understanding at the Molecular Level Bengt Jönsson Mikael Landgren Gerd Olofsson 115

5 Solubilization in Mixed Micelles Nagamune Nishikido 143

6 Solubilization in Amphophilic Copolymer Solutions Patricia N. Hurter Paschalis Alexandridis T. Alan Hatton 191

7 Kinetics of Solubilization in Surfactant-Based Systems Anthony J. Ward 237

III Solubilization in Nonmicellar Surfactant Aggregates

8 Adsolubilization John H. O'Haver Jeffrey H. Harwell Lance L. Lobban Edgar A. O'Rear III 277

9 Solubilization in Micelles and Vesicles Studied by Fluorescence Techniques: Interplay Between the Microproperties of the Aggregates and the Locus and Extent of Solubilization Eduardo Lissi Elsa Abuin 297

10 Solubilization of Organic Compounds by Vesicles Masahiko Abe Hitoshi Yamauchi Keizo Ogino 333

IV Methods of Measuring Solubilization

11 Solubilization, as Studied by Nuclear Spin Relaxation and NMR-Based Self-Diffusion Techniques Peter Stilbs 367

12 The Partitioning of Neutral Solutes Between Micelles and Water as Deduced from Critical Micelle Concentration Determinations C. Treiner 383

13 Vapor Pressure Studies of Solubilization Edwin E. Tucker 429

14 Comparison of Experimental Methods for the Determination of the Partition Coefficients of n-Alcohols in SDS and DTAB Micelles D. Gerrard Marangoni Jan C. T. Kwak 455

V Applications of Solubilization

15 Solubilization and Detergency Guy Broze 493

16 Solubilization in Micellar Separations Timothy J. Ward Karen D. Ward 517

Index 541

Editorial Reviews

"This volume consisting of the valuable contributions from about thirty-two experts in the field is remarkable for its contents and the critical review of the different aspects concerning solubilization in surfactant aggregates.. . .a valuable addition to any scientific library. "
—-Bulletin of Electrochemistry
". . .there are numerous references to applications and empirical data, which would be very useful to the practical chemist. "
—-Chemistry & Industry

From the Publisher