Gold-Catalyzed Cycloisomerization Reactions Through Activation of Alkynes: New Developments and Mechanistic Studies

Gold-Catalyzed Cycloisomerization Reactions Through Activation of Alkynes: New Developments and Mechanistic Studies

by Antoine Simonneau

Paperback(Softcover reprint of the original 1st ed. 2014)

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Product Details

ISBN-13: 9783319360973
Publisher: Springer International Publishing
Publication date: 10/28/2016
Series: Springer Theses
Edition description: Softcover reprint of the original 1st ed. 2014
Pages: 245
Product dimensions: 6.10(w) x 9.25(h) x 0.02(d)

About the Author

Antoine Simonneau obtained his Ph. D. under the guidance of Profs. Louis Fensterbank and Max Malacria at the Université Pierre et Marie Curie (Paris). At this time he was involved in the development of new cycloisomerization reactions under gold catalysis and mechanistic studies. He is currently a Humboldt postdoctoral fellow in the laboratory of Prof. Martin Oestreich at the Technische Universität of Berlin, where he is working on catalysis with main group electrophiles.

Table of Contents

General Introduction Gold, a Powerful Tool for the Activation of C-C Multiple Bonds.- Gold and Platinum-Catalyzed Reactions of Enynes.- New Advances in the Gold-Catalyzed Cycloisomerization Reactions of Enynes: 1,5-hydride Shifts and Access to Ketomacrolactones.- Synthesis of Polyconjugated bis-Enones through a Gold-Catalyzed 1,3-Acyloxy Migration-Cyclization-1,5-Acyl Shift Cascade Reaction.- Tracking Gold Acetylides in Gold(I)-Catalyzed Cycloisomerization Reactions of 1,6-Enynes.- General Conclusion.- Experimental Section.

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