Metallomacrocycles: From Structures to Applications

The metal–ligand coordination of metallomacrocycles allows for the production of both discrete and infinite metallosupramolecular structures with high-degrees of complexity. In recent years, coordination-driven self-assembly has emerged as a powerful noncovalent synthetic strategy to build discrete supramolecular architectures with diverse coordination moieties such as a well-defined shape, size, and geometry. The dynamic features of the metal–ligand bonds result in structures with intrigui...