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This book highlights recent advances in the discipline of biogeochemistry that have directly resulted from the development of critical zone (CZ) science. The earth's critical zone (CZ) is defined from the weathering front and lowest extent of freely circulating groundwater up through the regolith and to the top of the vegetative canopy. The structure and function of the CZ is shaped through tectonic, lithologic, hydrologic, climatic, and biological processes and is the result of processes o...